Organometallic Radical-Initiated Cleavage of the Metal Chelate and Thiazole Rings in a Cyclopentadienylchromium Complex

Extensive ring cleavage in the mercaptobenzothiazole chromium complex CpCr(CO)2(SCSN(C6H4)) (2), initiated by cyclopentadienyl chromium tricarbonyl, produced novel polynuclear complexes 3−5.

Saved in:
Bibliographic Details
Published inJournal of the American Chemical Society Vol. 124; no. 30; pp. 8804 - 8805
Main Authors Goh, Lai Yoong, Weng, Zhiqiang, Leong, Weng Kee, Vittal, Jagadese J
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 31.07.2002
Subjects
Chelating Agents - chemistry
Chemical reactivity
Chemistry
Chromium - chemistry
Cyclopentanes - chemistry
Exact sciences and technology
Molecular Structure
Organic chemistry
Organometallic Compounds - chemistry
Reactivity and mechanisms
Thiazoles - chemistry
X-Ray Diffraction
Sulfur nitrogen heterocycle
Chromium Organic compounds
Molecular structure
Chromium Carbonyl Complexes
Reaction path
Bicyclic compound
Transition metal Carbonyl Complexes
Aromatic compound
Benzothiazole derivatives
Experimental study
Chemical reactivity
Online AccessGet full text

Cover

More Information
Summary:Extensive ring cleavage in the mercaptobenzothiazole chromium complex CpCr(CO)2(SCSN(C6H4)) (2), initiated by cyclopentadienyl chromium tricarbonyl, produced novel polynuclear complexes 3−5.
Bibliography:ark:/67375/TPS-Q07KRH7P-N
istex:06DB4784218A5CEB645E6D7C7B46D64B53DABDFB
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja026335t