Metal–Organic Pathways for Anisotropic Growth of a Highly Symmetrical Crystal Structure: Example of the fcc Ni

• Published in: Langmuir Vol. 29; no. 44; pp. 13491 - 13501
• Main Authors: Mourdikoudis, Stefanos, Collière, Vincent, Amiens, Catherine, Fau, Pierre, Kahn, Myrtil L
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 05.11.2013
• Subjects: Anisotropy; Chemical Sciences; Chemical synthesis methods; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Coordination chemistry; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Magnetic properties and materials; Magnetic properties of nanostructures; Materials science; Metal Nanoparticles - chemistry; Methods of nanofabrication; Nickel - classification; Organic Chemicals - chemistry; Physics; Crystal growth; Organometallic compounds; Operating mode; Magnetic hysteresis; Precursor; Transmission electron microscopy; Anisotropy; Nickel; Crystal morphology; Chemical synthesis; Nanocrystal; Nanomaterial synthesis; Crystal structure
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la402001t

The control of the metallic nanocrystal shape is of prime importance for a wide variety of applications. We report a detailed research work on metal–organic chemical routes for the synthesis of a highly symmetrical crystal structure. In particular, this study shows the key parameters ensuring the anisotropic growth of nickel nanostructures (fcc crystal). Numerous reaction conditions are investigated (precursors, solvents, temperature, reducing agents, reaction time, and types and ratios of surfactants, such as alkyl amines, carboxylic acids, and phosphine oxides), and their effects on the size and shape of the final product are reported. The role of the growth modifiers and the structuring of the reaction media on the anisotropic growth are demonstrated. This metal–organic approach generates several novel anisotropic nanostructures in a wide size range depending on the reaction conditions. In this way, nanomaterials with reproducible size, shape, and composition are obtained with good yield. Transmission electron microscopy techniques (TEM and HRTEM) are the principal methods for monitoring the morphology.