Synthesis and Mesomorphic Behavior of a Donor−Acceptor-Type Hexaazatriphenylene

A new donor-acceptor, 1,4,5,8,9,12-hexaazatriphenylene HATCNOR n , is described. The synthesis of HATCNOR1 and HATCNOR6 is achieved by the regioselective displacement of 1,4,5,8,9,12-hexaazatriphenylene hexacarbonitrile (HATCN) with an alkoxy group. The X-ray analysis revealed self-assembly of HATCN...

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Bibliographic Details
Published inOrganic letters Vol. 7; no. 19; pp. 4075 - 4078
Main Authors Chang, Tsu-Hsin, Wu, Bi-Ru, Chiang, Michael Y, Liao, Su-Chih, Ong, Chi Wi, Hsu, Hsiu-Fu, Lin, Shu-Yu
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 15.09.2005
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
MOLECULAR-STRUCTURE
DISCOTIC LIQUID-CRYSTALS
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Summary:A new donor-acceptor, 1,4,5,8,9,12-hexaazatriphenylene HATCNOR n , is described. The synthesis of HATCNOR1 and HATCNOR6 is achieved by the regioselective displacement of 1,4,5,8,9,12-hexaazatriphenylene hexacarbonitrile (HATCN) with an alkoxy group. The X-ray analysis revealed self-assembly of HATCNOR1 in the solid state. HATCNOR6 is the new difunctionalized hexaazatriphenylene discotic liquid crystal.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol051231j