Unexpected One-Pot Method to Synthesize Spiro[fluorene-9,9‘-xanthene] Building Blocks for Blue-Light-Emitting Materials

An unexpected one-pot synthetic approach toward spiro[fluorene-9,9‘-xanthene] (SFX) under excessive MeSO3H conditions has been developed. The key step involves a thermodynamically controlled cyclization reaction. Blue-light-emitting materials based on SFX building blocks that exhibit high thermal st...

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Bibliographic Details
Published inOrganic letters Vol. 8; no. 13; pp. 2787 - 2790
Main Authors Xie, Ling-Hai, Liu, Feng, Tang, Chao, Hou, Xiao-Ya, Hua, Yu-Ran, Fan, Qu-Li, Huang, Wei
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 22.06.2006
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
RECOGNITION
RECEPTORS
DERIVATIVES
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Summary:An unexpected one-pot synthetic approach toward spiro[fluorene-9,9‘-xanthene] (SFX) under excessive MeSO3H conditions has been developed. The key step involves a thermodynamically controlled cyclization reaction. Blue-light-emitting materials based on SFX building blocks that exhibit high thermal stability have also been synthesized.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol060871z