Heteroleptic Dipyrrin/Bipyridine Complexes of Ruthenium(II)

The synthesis and characterization of a series of heteroleptic dipyrrinato/2,2′-bipyridine complexes of ruthenium(II) are reported. Spectroscopic analysis, including resonance Raman, indicates that the complexes are only weakly emissive and that the dipyrrin and Ru → bipyridine (metal-to-ligand char...

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Published inInorganic chemistry Vol. 48; no. 1; pp. 13 - 15
Main Authors Smalley, Serena J, Waterland, Mark R, Telfer, Shane G
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 05.01.2009
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Summary:The synthesis and characterization of a series of heteroleptic dipyrrinato/2,2′-bipyridine complexes of ruthenium(II) are reported. Spectroscopic analysis, including resonance Raman, indicates that the complexes are only weakly emissive and that the dipyrrin and Ru → bipyridine (metal-to-ligand charge transfer) chromophores are uncoupled.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic8016497