Highly Enantioselective Copper-Catalyzed Conjugate Addition of Diethylzinc to Nitroalkenes

Copper-catalyzed asymmetric conjugate addition of diethylzinc to nitroalkenes using new chiral monodentate phosphoramidite ligands proceeds with high enantioselectivity up to 99% ee.

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Bibliographic Details
Published inOrganic letters Vol. 6; no. 16; pp. 2689 - 2691
Main Authors Choi, Hojae, Hua, Zihao, Ojima, Iwao
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 05.08.2004
Amer Chemical Soc
Subjects
Alkenes - chemistry
Catalysis
Chemistry
Chemistry, Organic
Copper - chemistry
Ligands
Nitro Compounds - chemistry
Organometallic Compounds - chemistry
Organophosphorus Compounds - chemistry
Physical Sciences
Science & Technology
Stereoisomerism
NITROOLEFINS
ENONES
DIALKYLZINC REAGENTS
LIGANDS
ZINC
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Summary:Copper-catalyzed asymmetric conjugate addition of diethylzinc to nitroalkenes using new chiral monodentate phosphoramidite ligands proceeds with high enantioselectivity up to 99% ee.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol0491282