Synthesis and Magnetic Properties of Wheel-Shaped [Mn12] and [Fe6] Complexes

The reactions of the ligands N-methyldiethanol amine and N-ethyldiethanol amine (abbreviated H2mdea and H2edea, respectively) with [Mn12O12(O2CCH3)16(H2O)4] yield novel dodecanuclear wheel-shaped products. The capability of the ligands H2mdea and H2edea to support wheel structures in metals other th...

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Published inInorganic chemistry Vol. 43; no. 21; pp. 6531 - 6533
Main Authors Rumberger, Evan M, Zakharov, Lev N, Rheingold, Arnold L, Hendrickson, David N
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 18.10.2004
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Summary:The reactions of the ligands N-methyldiethanol amine and N-ethyldiethanol amine (abbreviated H2mdea and H2edea, respectively) with [Mn12O12(O2CCH3)16(H2O)4] yield novel dodecanuclear wheel-shaped products. The capability of the ligands H2mdea and H2edea to support wheel structures in metals other than Mn is demonstrated with the crystal structure of a new hexanuclear ferric wheel.
Bibliography:ObjectType-Article-1
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic0488886