Structure, Reactivity, and Computational Studies of a Novel Ruthenium Hydrogen Sulfide Dihydride Complex

Addition of 1 atm of H2S to [Ru(IMes)2(CO)(EtOH)H2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)(H2S)H2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes)2...

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Published inInorganic chemistry Vol. 42; no. 24; pp. 7695 - 7697
Main Authors Chatwin, Sarah L, Diggle, Richard A, Jazzar, Rodolphe F. R, Macgregor, Stuart A, Mahon, Mary F, Whittlesey, Michael K
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 01.12.2003
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Summary:Addition of 1 atm of H2S to [Ru(IMes)2(CO)(EtOH)H2] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords the air-stable hydrogen sulfide dihydride complex, [Ru(IMes)2(CO)(H2S)H2] 2. Treatment of 2 with excess H2S leads to formation of the 16-electron bis-hydrosulfido complex, [Ru(IMes)2(CO)(SH)2] 3. Preliminary studies show that 3 reacts with both H2 and CO in solution as well as in the solid state. Both 2 and 3 have been structurally characterized
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content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/ic030241i