Synthesis of Novel Amorphous Boron Carbonitride Ceramics from the Borazine Derivative Copolymer via Hydroboration

A preceramic polymer for boron carbonitride was synthesized for the first time by the hydroboration of borazine derivatives, B-triethynyl, N-trimethyl borazine and borazine, without a catalyst. A homogeneous, amorphous boron carbonitride ceramic was prepared by the thermolysis of a hydroborated copo...

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Published inInorganic chemistry Vol. 43; no. 16; pp. 4796 - 4798
Main Authors Jeon, Jong-Kyu, Uchimaru, Yuko, Kim, Dong-Pyo
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 09.08.2004
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Summary:A preceramic polymer for boron carbonitride was synthesized for the first time by the hydroboration of borazine derivatives, B-triethynyl, N-trimethyl borazine and borazine, without a catalyst. A homogeneous, amorphous boron carbonitride ceramic was prepared by the thermolysis of a hydroborated copolymer in an argon atmosphere.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:0020-1669
1520-510X
DOI:10.1021/ic035254a