Synthesis of 1,2,3,7,8,9-Hexahydrodipyrrins and Secocorrins: † Important Precursors for the Construction of Corrins

Hexahydrodipyrrins 15 (X = H2) have been prepared by two routes:  Pd(0)-initiated coupling/cyclization of triflates 11 and alkyne amines 12 and reduction of semicorrins 26 (X = O).

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Bibliographic Details
Published inOrganic letters Vol. 1; no. 2; pp. 341 - 344
Main Authors Jacobi, Peter A, Liu, Hui
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 29.07.1999
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Chromatography, Thin Layer
Corrinoids
Cyclization
Oxidation-Reduction
Physical Sciences
Porphyrins - chemical synthesis
Pyrroles - chemical synthesis
Science & Technology
VITAMIN-B12
HALIDES
ARYL
ISOBACTERIOCHLORINS
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Summary:Hexahydrodipyrrins 15 (X = H2) have been prepared by two routes:  Pd(0)-initiated coupling/cyclization of triflates 11 and alkyne amines 12 and reduction of semicorrins 26 (X = O).
Bibliography:Medline
NIH RePORTER
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol990684j