Facile Preparation of Boron and Nitrogen Codoped Green Emission Carbon Quantum Dots for Detection of Permanganate and Captopril

• Published in: Analytical chemistry (Washington) Vol. 91; no. 17; pp. 11455 - 11460
• Main Authors: Jiang, Xiaohua, Qin, Dongmiao, Mo, Guichun, Feng, Jinsu, Zheng, Xiangfei, Deng, Biyang
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 03.09.2019
• Subjects: Boric acid; Boron; Captopril; Carbon; Chemistry; Emission spectra; Ethylene glycol; Fluorescence; Nitrogen; Quantum dots; Quenching; Salicylic acid; Wavelengths
• ISSN: 0003-2700; 1520-6882
• DOI: 10.1021/acs.analchem.9b02938

A hydrothermal strategy for preparing boron and nitrogen codoped carbon quantum dots was studied using the precursors of p-amino salicylic acid, boric acid and ethylene glycol dimethacrylate. The boron and nitrogen codoped carbon quantum dots have high fluorescence intensity, good monodispersity, high stability, superior water solubility, and a fluorescence quantum yield of 19.6%. Their average size is 5 nm. Their maximum excitation and emission wavelengths are 380 and 520 nm, respectively. Permanganate (MnO4 –) quenched boron and nitrogen codoped carbon quantum dots fluorescence through inner filter effect and static quenching effects. The linear relation between quenching efficiency and MnO4 – concentration ranged from 0.05 to 60 μmol/L with a detection limit of 13 nmol/L. In the presence of captopril, MnO4 – was reduced to Mn2+ and the fluorescence of boron and nitrogen codoped carbon quantum dots was recovered. The linear range between recovery and captopril concentration was from 0.1 to 60 μmol/L. The limit of detection was 0.03 μmol/L. The developed method can be employed as a sensitive fluorescence sensing platform for MnO4 –. It has been successfully used for captopril detection in mouse plasma.