Toward Rational Design of Cu/SSZ-13 Selective Catalytic Reduction Catalysts: Implications from Atomic-Level Understanding of Hydrothermal Stability
The hydrothermal stability of Cu/SSZ-13 SCR catalysts has been extensively studied, yet atomic-level understanding of changes to the zeolite support and the Cu active sites during hydrothermal aging are still lacking. In this work, via the utilization of spectroscopic methods including solid-state 2...
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| Published in | ACS catalysis Vol. 7; no. 12; pp. 8214 - 8227 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
01.12.2017
American Chemical Society (ACS) |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The hydrothermal stability of Cu/SSZ-13 SCR catalysts has been extensively studied, yet atomic-level understanding of changes to the zeolite support and the Cu active sites during hydrothermal aging are still lacking. In this work, via the utilization of spectroscopic methods including solid-state 27Al and 29Si NMR, EPR, DRIFTS, and XPS, together with imaging and elemental mapping using STEM, detailed kinetic analyses, and theoretical calculations with DFT, various Cu species, including two types of isolated active sites and CuOx clusters, were precisely quantified for samples hydrothermally aged under varying conditions. This quantification convincingly confirms the exceptional hydrothermal stability of isolated Cu2+-2Z sites and the gradual conversion of [Cu(OH)]+-Z to CuOx clusters with increasing aging severity. This stability difference is rationalized from the hydrolysis activation barrier difference between the two isolated sites via DFT. Discussions are provided on the nature of the CuOx clusters and their possible detrimental roles on catalyst stability. Finally, a few rational design principles for Cu/SSZ-13 are derived rigorously from the atomic-level understanding of this catalyst obtained here. |
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| AbstractList | The hydrothermal stability of Cu/SSZ-13 SCR catalysts has been extensively studied, yet atomic level understanding of changes to the zeolite support and the Cu active sites during hydrothermal aging are still lacking. In this work, via the utilization of spectroscopic methods including solid-state 27Al and 29Si NMR, EPR, DRIFTS, and XPS, together with imaging and elemental mapping using STEM, detailed kinetic analyses, and theoretical calculations with DFT, various Cu species, including two types of isolated active sites and CuOx clusters, were precisely quantified for samples hydrothermally aged under varying conditions. This quantification convincingly confirms the exceptional hydrothermal stability of isolated Cu2+-2Z sites, and the gradual conversion of [Cu(OH)]+-Z to CuOx clusters with increasing aging severity. This stability difference is rationalized from the hydrolysis activation barrier difference between the two isolated sites via DFT. Discussions are provided on the nature of the CuOx clusters, and their possible detrimental roles on catalyst stability. Finally, a few rational design principles for Cu/SSZ-13 are derived rigorously from the atomic-level understanding of this catalyst obtained here. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. Computing time was granted by a user proposal at the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) and by the National Energy Research Scientific Computing Center (NERSC). The experimental studies described in this paper were performed in the EMSL, a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle. The hydrothermal stability of Cu/SSZ-13 SCR catalysts has been extensively studied, yet atomic-level understanding of changes to the zeolite support and the Cu active sites during hydrothermal aging are still lacking. In this work, via the utilization of spectroscopic methods including solid-state 27Al and 29Si NMR, EPR, DRIFTS, and XPS, together with imaging and elemental mapping using STEM, detailed kinetic analyses, and theoretical calculations with DFT, various Cu species, including two types of isolated active sites and CuOx clusters, were precisely quantified for samples hydrothermally aged under varying conditions. This quantification convincingly confirms the exceptional hydrothermal stability of isolated Cu2+-2Z sites and the gradual conversion of [Cu(OH)]+-Z to CuOx clusters with increasing aging severity. This stability difference is rationalized from the hydrolysis activation barrier difference between the two isolated sites via DFT. Discussions are provided on the nature of the CuOx clusters and their possible detrimental roles on catalyst stability. Finally, a few rational design principles for Cu/SSZ-13 are derived rigorously from the atomic-level understanding of this catalyst obtained here. |
| Author | Peden, Charles H. F Prodinger, Sebastian Walter, Eric D Mei, Donghai Song, James Wang, Yilin Kovarik, Libor Gao, Feng Washton, Nancy M Engelhard, Mark H Wang, Yong |
| AuthorAffiliation | Environmental Molecular Sciences Laboratory Institute for Integrated Catalysis Washington State University The Gene & Linda Voiland School of Chemical Engineering and Bioengineering Pacific Northwest National Laboratory |
| AuthorAffiliation_xml | – name: The Gene & Linda Voiland School of Chemical Engineering and Bioengineering – name: Washington State University – name: Institute for Integrated Catalysis – name: Pacific Northwest National Laboratory – name: Environmental Molecular Sciences Laboratory |
| Author_xml | – sequence: 1 givenname: James surname: Song fullname: Song, James organization: Washington State University – sequence: 2 givenname: Yilin surname: Wang fullname: Wang, Yilin organization: Pacific Northwest National Laboratory – sequence: 3 givenname: Eric D surname: Walter fullname: Walter, Eric D organization: Pacific Northwest National Laboratory – sequence: 4 givenname: Nancy M orcidid: 0000-0002-9643-6794 surname: Washton fullname: Washton, Nancy M organization: Pacific Northwest National Laboratory – sequence: 5 givenname: Donghai orcidid: 0000-0002-0286-4182 surname: Mei fullname: Mei, Donghai email: donghai.mei@pnnl.gov organization: Pacific Northwest National Laboratory – sequence: 6 givenname: Libor surname: Kovarik fullname: Kovarik, Libor organization: Pacific Northwest National Laboratory – sequence: 7 givenname: Mark H surname: Engelhard fullname: Engelhard, Mark H organization: Pacific Northwest National Laboratory – sequence: 8 givenname: Sebastian orcidid: 0000-0001-8749-0476 surname: Prodinger fullname: Prodinger, Sebastian organization: Pacific Northwest National Laboratory – sequence: 9 givenname: Yong orcidid: 0000-0002-8460-7410 surname: Wang fullname: Wang, Yong organization: Washington State University – sequence: 10 givenname: Charles H. F surname: Peden fullname: Peden, Charles H. F organization: Pacific Northwest National Laboratory – sequence: 11 givenname: Feng orcidid: 0000-0002-8450-3419 surname: Gao fullname: Gao, Feng email: feng.gao@pnnl.gov organization: Pacific Northwest National Laboratory |
| BackLink | https://www.osti.gov/biblio/1419918$$D View this record in Osti.gov |
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| Cites_doi | 10.1016/j.apcatb.2010.12.022 10.1039/c2cp43467a 10.1016/j.apcatb.2017.06.013 10.1021/acscatal.5b01621 10.1021/jacs.6b10169 10.1016/j.jcat.2016.04.021 10.1016/S0021-9517(02)00112-4 10.1016/j.cpc.2004.12.014 10.1557/PROC-111-235 10.1002/anie.201303498 10.1021/cs501673g 10.1016/0039-6028(94)00731-4 10.1016/j.jcat.2011.12.025 10.1039/C3CP54132K 10.1039/c1cc12469b 10.1016/j.jcat.2017.02.025 10.1021/acscatal.5b01496 10.1016/j.jcat.2014.08.010 10.1016/j.cattod.2010.03.055 10.1002/cctc.201300141 10.1103/PhysRevB.58.3641 10.1081/CR-120023908 10.1021/cs500563s 10.1063/1.2770708 10.1002/anie.201104462 10.1016/j.cattod.2015.12.002 10.1039/c2cc31184d 10.1007/s10562-012-0771-y 10.1016/S1387-1811(03)00339-1 10.1107/S2052252514020181 10.1016/j.jcat.2014.01.004 10.1016/j.jcat.2013.12.012 10.1021/acscatal.5b01200 10.1006/jcat.2002.3521 10.1021/cr00007a010 10.1146/annurev-physchem-032511-143722 10.1016/j.apcatb.2014.02.037 10.1021/jacs.6b02651 10.1016/j.apcatb.2016.08.053 10.1039/b001167n 10.1016/j.apcatb.2013.09.010 10.1039/C5CC02670A 10.1016/j.cattod.2011.10.034 10.1016/j.cattod.2013.10.047 10.1016/S0079-6816(99)00012-X 10.1081/CR-200031932 10.1002/anie.201407030 10.1021/la991011c 10.1039/C5CC05980A 10.1002/anie.200462473 10.1039/C5CS00108K 10.1021/acs.jpclett.5b00069 10.1016/j.apcatb.2014.03.030 10.1016/j.apcata.2012.03.026 10.1021/jacs.7b01128 10.1021/jp5065616 10.1103/PhysRevLett.77.3865 10.1021/acscatal.6b03679 10.1103/PhysRevB.54.1703 10.1007/978-1-4899-8071-7 10.1016/j.jcat.2014.03.003 10.1016/j.jcat.2013.10.017 10.1006/jcat.1997.1739 10.1007/s11244-013-0145-8 10.1016/j.jcat.2014.01.017 10.1016/j.apcatb.2014.10.020 10.1039/f19898504091 10.1021/jz500241m 10.1063/1.1329672 10.1016/j.jcat.2012.12.020 10.1016/j.jcat.2015.08.004 10.1021/jp4028468 10.1039/c3dt50732g |
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| References | ref9/cit9 ref45/cit45 ref27/cit27 ref63/cit63 ref56/cit56 ref16/cit16 ref52/cit52 ref23/cit23 ref8/cit8 ref31/cit31 ref59/cit59 ref2/cit2 Nova I. (ref3/cit3) 2014 ref34/cit34 ref71/cit71 ref37/cit37 ref20/cit20 ref48/cit48 ref60/cit60 ref74/cit74 ref17/cit17 ref10/cit10 ref35/cit35 ref53/cit53 ref19/cit19 ref21/cit21 ref42/cit42 ref46/cit46 ref49/cit49 ref13/cit13 ref61/cit61 ref67/cit67 ref24/cit24 ref38/cit38 ref50/cit50 ref64/cit64 ref54/cit54 ref6/cit6 ref36/cit36 ref18/cit18 ref65/cit65 ref11/cit11 ref25/cit25 ref29/cit29 ref72/cit72 ref32/cit32 ref39/cit39 ref14/cit14 ref57/cit57 ref5/cit5 ref51/cit51 ref43/cit43 ref28/cit28 ref40/cit40 ref68/cit68 ref26/cit26 ref55/cit55 ref73/cit73 ref69/cit69 ref12/cit12 ref15/cit15 ref62/cit62 ref66/cit66 ref41/cit41 ref58/cit58 ref22/cit22 ref33/cit33 ref4/cit4 ref30/cit30 ref47/cit47 ref1/cit1 ref44/cit44 ref70/cit70 ref7/cit7 |
| References_xml | – ident: ref74/cit74 doi: 10.1016/j.apcatb.2010.12.022 – ident: ref15/cit15 doi: 10.1039/c2cp43467a – ident: ref34/cit34 doi: 10.1016/j.apcatb.2017.06.013 – ident: ref12/cit12 doi: 10.1021/acscatal.5b01621 – ident: ref71/cit71 doi: 10.1021/jacs.6b10169 – ident: ref65/cit65 doi: 10.1016/j.jcat.2016.04.021 – ident: ref68/cit68 doi: 10.1016/S0021-9517(02)00112-4 – ident: ref42/cit42 doi: 10.1016/j.cpc.2004.12.014 – ident: ref54/cit54 doi: 10.1557/PROC-111-235 – ident: ref14/cit14 doi: 10.1002/anie.201303498 – ident: ref25/cit25 doi: 10.1021/cs501673g – ident: ref50/cit50 doi: 10.1016/0039-6028(94)00731-4 – ident: ref5/cit5 doi: 10.1016/j.jcat.2011.12.025 – ident: ref21/cit21 doi: 10.1039/C3CP54132K – ident: ref30/cit30 doi: 10.1039/c1cc12469b – ident: ref41/cit41 doi: 10.1016/j.jcat.2017.02.025 – ident: ref48/cit48 doi: 10.1021/acscatal.5b01496 – ident: ref9/cit9 doi: 10.1016/j.jcat.2014.08.010 – ident: ref51/cit51 doi: 10.1016/j.cattod.2010.03.055 – ident: ref31/cit31 doi: 10.1002/cctc.201300141 – ident: ref44/cit44 doi: 10.1103/PhysRevB.58.3641 – ident: ref56/cit56 doi: 10.1081/CR-120023908 – ident: ref64/cit64 doi: 10.1021/acscatal.5b01496 – ident: ref24/cit24 doi: 10.1021/cs500563s – ident: ref46/cit46 doi: 10.1063/1.2770708 – ident: ref62/cit62 doi: 10.1002/anie.201104462 – ident: ref27/cit27 doi: 10.1016/j.cattod.2015.12.002 – ident: ref7/cit7 doi: 10.1039/c2cc31184d – ident: ref6/cit6 doi: 10.1007/s10562-012-0771-y – ident: ref53/cit53 doi: 10.1016/S1387-1811(03)00339-1 – ident: ref16/cit16 doi: 10.1107/S2052252514020181 – ident: ref17/cit17 doi: 10.1016/j.jcat.2014.01.004 – ident: ref39/cit39 doi: 10.1016/j.jcat.2013.12.012 – ident: ref66/cit66 doi: 10.1021/acscatal.5b01200 – ident: ref52/cit52 doi: 10.1006/jcat.2002.3521 – ident: ref57/cit57 doi: 10.1021/cr00007a010 – ident: ref67/cit67 doi: 10.1146/annurev-physchem-032511-143722 – ident: ref40/cit40 doi: 10.1016/j.apcatb.2014.02.037 – ident: ref28/cit28 doi: 10.1021/jacs.6b02651 – ident: ref11/cit11 doi: 10.1016/j.apcatb.2016.08.053 – ident: ref45/cit45 doi: 10.1039/b001167n – ident: ref61/cit61 doi: 10.1016/j.apcatb.2013.09.010 – ident: ref32/cit32 doi: 10.1039/C5CC02670A – ident: ref36/cit36 doi: 10.1016/j.cattod.2011.10.034 – ident: ref38/cit38 doi: 10.1016/j.cattod.2013.10.047 – ident: ref69/cit69 doi: 10.1016/S0079-6816(99)00012-X – ident: ref1/cit1 doi: 10.1081/CR-200031932 – ident: ref22/cit22 doi: 10.1002/anie.201407030 – ident: ref55/cit55 doi: 10.1021/la991011c – ident: ref33/cit33 doi: 10.1039/C5CC05980A – ident: ref70/cit70 doi: 10.1002/anie.200462473 – ident: ref2/cit2 doi: 10.1039/C5CS00108K – ident: ref26/cit26 doi: 10.1021/acs.jpclett.5b00069 – ident: ref35/cit35 doi: 10.1016/j.apcatb.2014.03.030 – ident: ref37/cit37 doi: 10.1016/j.apcata.2012.03.026 – ident: ref29/cit29 doi: 10.1021/jacs.7b01128 – ident: ref19/cit19 doi: 10.1021/jp5065616 – ident: ref47/cit47 doi: 10.1103/PhysRevLett.77.3865 – ident: ref59/cit59 doi: 10.1021/acscatal.6b03679 – ident: ref43/cit43 doi: 10.1103/PhysRevB.54.1703 – volume-title: Urea-SCR Technology for deNOx After Treatment of Diesel Exhausts year: 2014 ident: ref3/cit3 doi: 10.1007/978-1-4899-8071-7 – ident: ref20/cit20 doi: 10.1016/j.jcat.2014.03.003 – ident: ref73/cit73 doi: 10.1016/j.jcat.2013.10.017 – ident: ref60/cit60 doi: 10.1006/jcat.1997.1739 – ident: ref4/cit4 doi: 10.1007/s11244-013-0145-8 – ident: ref23/cit23 doi: 10.1016/j.jcat.2014.01.017 – ident: ref72/cit72 doi: 10.1016/j.apcatb.2014.10.020 – ident: ref58/cit58 doi: 10.1039/f19898504091 – ident: ref18/cit18 doi: 10.1021/jz500241m – ident: ref49/cit49 doi: 10.1063/1.1329672 – ident: ref8/cit8 doi: 10.1016/j.jcat.2012.12.020 – ident: ref10/cit10 doi: 10.1016/j.jcat.2015.08.004 – ident: ref63/cit63 doi: 10.1021/jp4028468 – ident: ref13/cit13 doi: 10.1039/c3dt50732g |
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| Snippet | The hydrothermal stability of Cu/SSZ-13 SCR catalysts has been extensively studied, yet atomic-level understanding of changes to the zeolite support and the Cu... The hydrothermal stability of Cu/SSZ-13 SCR catalysts has been extensively studied, yet atomic level understanding of changes to the zeolite support and the Cu... |
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| SubjectTerms | Cu/SSZ-13 DRIFTS Environmental Molecular Sciences Laboratory EPR hydrothermal aging NMR selective catalytic reduction TEM |
| Title | Toward Rational Design of Cu/SSZ-13 Selective Catalytic Reduction Catalysts: Implications from Atomic-Level Understanding of Hydrothermal Stability |
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