Tailings Weathering and Arsenic Mobility at the Abandoned Zgounder Silver Mine, Morocco

• Published in: Mine water and the environment Vol. 35; no. 4; pp. 508 - 524
• Main Authors: El Adnani, M., Plante, B., Benzaazoua, M., Hakkou, R., Bouzahzah, H.
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.12.2016; Springer Nature B.V
• Subjects: Acid mine drainage; Acidity; Arsenic; Carbonates; Chlorite; Cobalt; Contaminants; Copper; Dolomite; Dolostone; Drainage; Drainage water; Earth and Environmental Science; Earth Sciences; Ecotoxicology; Galena; Geology; Hydrogeology; Industrial Pollution Prevention; Iron; Leachates; Lead; Low concentrations; Manganese; Mine tailings; Mine wastes; Mineral Resources; Muscovite; Orthoclase; Oxidation; Oxides; Pyrite; Salts; Silicates; Silver; Sorption; Sphalerite; Sulfides; Sulphides; Tailings; Technical Article; Titanium; Trace elements; Water chemistry; Water Quality/Water Pollution; Weathering; Zinc; Zincblende; Morocco; Sorption; Geochemical behavior; Acid mine drainage; Contaminated neutral drainage; Weathering cells
• ISSN: 1025-9112; 1616-1068
• DOI: 10.1007/s10230-015-0370-4

The abandoned Zgounder Mine (Morocco) was exploited for Ag from 1982 to 1990 and generated nearly 490,000 t of mill tailings before it was closed without being reclaimed. The tailings contain low concentrations of sulfide (mainly as pyrite, sphalerite, and galena) and carbonates (mainly dolomite). Silicates (muscovite, albite, chlorite, labradorite, actinolite, and orthoclase) occur in high concentrations. The most abundant trace elements are As, Ti, Fe, Mn, Zn, and Pb. We studied the geochemical behavior of the mine wastes to identify the main factors controlling drainage water chemistry. Particular emphasis was put on sorption phenomena to explain the low As concentrations in the leachates despite significant As levels in the tailings. Weathering cell tests carried out on various tailings produced two types of contaminated drainage: acidic and neutral. The kinetic test leachates contained high concentrations of some contaminants, including As (0.8 mg L −1 ), Co (11 mg L −1 ), Cu (34 mg L −1 ), Fe (70 mg L −1 ), Mn (126 mg L −1 ), and Zn (314 mg L −1 ). Acidity and contaminants in the leachates were controlled by dissolution of soluble salts and Fe hydrolysis rather than sulfide oxidation. Batch sorption tests quantified the significance of As sorption, and sequential extraction showed that most of the As sorption was associated with the reducible fractions (Fe and Mn oxides and oxyhydroxides).