Redox-Active Tin Metal–Organic Framework with a Thiolate-Based Ligand

Metal–organic frameworks (MOFs) and coordination polymers composed of thiolates as coordinating functional groups are interesting materials with unique optical and electronical properties. Herein, we report the preparation of KGF-4 and KGF-10, two Sn-MOF crystal structures with bonds between Sn and...

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Published inInorganic chemistry Vol. 60; no. 17; pp. 12691 - 12695
Main Authors Kamakura, Yoshinobu, Fujisawa, Satoshi, Takahashi, Koki, Toshima, Hiroki, Nakatani, Yuka, Yoshikawa, Hirofumi, Saeki, Akinori, Ogasawara, Kazuyoshi, Tanaka, Daisuke
Format Journal Article
LanguageEnglish
Published American Chemical Society 06.09.2021
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Summary:Metal–organic frameworks (MOFs) and coordination polymers composed of thiolates as coordinating functional groups are interesting materials with unique optical and electronical properties. Herein, we report the preparation of KGF-4 and KGF-10, two Sn-MOF crystal structures with bonds between Sn and thiolate. KGF-10 was isolated as a pure phase and found to exhibit redox properties and a semiconducting band structure, as confirmed by first-principles (density functional theory) calculations.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.1c01725