Fast Crystal Growth in o‑Terphenyl Glasses: A Possible Role for Fracture and Surface Mobility

• Published in: The journal of physical chemistry. B Vol. 119; no. 31; pp. 10124 - 10130
• Main Authors: Powell, C. Travis, Xi, Hanmi, Sun, Ye, Gunn, Erica, Chen, Yinshan, Ediger, M. D, Yu, Lian
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 06.08.2015
• Subjects: Calorimetry; Crack propagation; Crystal growth; Crystallization; Crystals; Density; Fracture mechanics; Glass; Glass - chemistry; Liquids; Microscopy, Electron, Scanning; Molecular Structure; Particle Size; Surface Properties; Temperature; Terphenyl Compounds - chemistry; Voids; X-Ray Diffraction
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/acs.jpcb.5b05389

Molecular liquids can develop a fast mode of crystal growth (“GC growth”) near the glass transition temperature. This phenomenon remains imperfectly understood with several explanations proposed. We report that GC growth in o-terphenyl conserves the overall volume, despite a 5% higher density of the crystal, and produces fine crystal grains with the same unit cell as normally grown crystals. These results indicate that GC growth continuously creates voids and free surfaces, possibly by fracture. This aspect of the phenomenon has not been considered by previous treatments and is a difficulty for those models that hypothesize a 5% strain without voids. Given the existence of even faster crystal growth on the free surface of molecular glasses, we consider the possibility that GC growth is facilitated by fracture and surface mobility. This notion has support from the fact that GC growth and surface growth are both highly correlated with surface diffusivity and with fast crystal growth along preformed cracks in the glass.