[(F6acac)Pd(μ-HNC6F5)]2, a Large Family of Polymorphs and Solvates with Short F···F Contacts

Highly fluorinated [(F6acac)­Pd­(μ-HNC6F5)]2 was prepared by the reaction of palladium bis­(hexa­fluoro­acetyl­acetonate), Pd­(F6acac)2, with pentafluoroaniline. This compound generates a large family of crystalline polymorphs and solvates. In this paper, we present a study on the synthesis, solutio...

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Published inACS omega Vol. 9; no. 5; pp. 5395 - 5405
Main Authors Kouton, Aniffa, Pepin, Robert, Maciulis, Nicholas Alexander, Gao, Xinfeng, Carta, Veronica, Siedle, Allen R.
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 06.02.2024
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Summary:Highly fluorinated [(F6acac)­Pd­(μ-HNC6F5)]2 was prepared by the reaction of palladium bis­(hexa­fluoro­acetyl­acetonate), Pd­(F6acac)2, with pentafluoroaniline. This compound generates a large family of crystalline polymorphs and solvates. In this paper, we present a study on the synthesis, solution phase dynamics, and crystal structures of highly fluorinated [(F6acac)­Pd­(μ-HNC6F5)]2. Pd3(μ-F6acac)2(μ-HNC6F5)4 is produced as a minor byproduct. We also describe the synthesis and structural characterization of trinuclear Pd3(μ-F6acac)3[μ-(CF3)2CN]3 prepared by the reaction of Pd­(F6acac)2 with hexafluoroacetone imine.
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ISSN:2470-1343
2470-1343
DOI:10.1021/acsomega.3c06550