Kinetics and Mechanism of the Thermolysis of 1,1-Dimethyl-1-germacyclohepta-2,4,6-triene

The thermolysis of 1,1-dimethyl-1-germacyclohepta-2,4,6-triene led to the formation of benzene and dimethylgermylene, as expected. The activation energy and thermodynamic data for the germylene extrusion reaction were determined to be E a = 21.2 ± 0.1 kcal/mol, ΔH ⧧ = 20.5 ± 0.1 kcal/mol, and ΔS ⧧ =...

Full description

Saved in:
Bibliographic Details
Published inOrganometallics Vol. 25; no. 17; pp. 4231 - 4233
Main Authors Mochida, Kunio, Matsuhisa, Nao, Sato, Ryuji, Nakadaira, Yasuhiro
Format Journal Article
LanguageEnglish
Published American Chemical Society 14.08.2006
Online AccessGet full text

Cover

More Information
Summary:The thermolysis of 1,1-dimethyl-1-germacyclohepta-2,4,6-triene led to the formation of benzene and dimethylgermylene, as expected. The activation energy and thermodynamic data for the germylene extrusion reaction were determined to be E a = 21.2 ± 0.1 kcal/mol, ΔH ⧧ = 20.5 ± 0.1 kcal/mol, and ΔS ⧧ = −8.1 ± 0.1 cal/(mol K), respectively.
Bibliography:ark:/67375/TPS-5MNLDT61-S
istex:0AEEB529ED3A496AD5EB9C3942CD233F95B10478
ISSN:0276-7333
1520-6041
DOI:10.1021/om0600689