Self-Assembled 3-D Architectures of BiOBr as a Visible Light-Driven Photocatalyst

• Published in: Chemistry of materials Vol. 20; no. 9; pp. 2937 - 2941
• Main Authors: Zhang, Jun, Shi, Fengjun, Lin, Jing, Chen, Dongfeng, Gao, Jianming, Huang, Zhixin, Ding, Xiaoxia, Tang, Chengcun
• Format: Journal Article
• Language: English
• Published: American Chemical Society 13.05.2008
• Subjects: Microstructure; Self-Assembly and Self-Assembled Materials; Semiconductors
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/cm7031898

In this work, we demonstrated the EG-assisted solvothermal synthesis of 3-D microspherical BiOBr architectures assembled by nanosheets. The morphology and compositional characteristics of the 3-D architectures were investigated by various microscopy techniques. The possible formation mechanism for the architectures was discussed. The band gap of the obtained BiOBr materials was estimated to be 2.54 eV by UV–vis. The specific surface area and porosity of the BiOBr 3-D architectures also were investigated by using nitrogen adsorption and desorption isotherms. Because of the narrow bandgap and the novel 3-D micro-/nanostructure, the BiOBr architectures show a more excellent photocatalytic activity under visible light irradiation than the BiOBr bulk plates. Several possible reasons for the higher photocatalytic activity have been taken into consideration. In addition, the photocatalyst is stable during the reaction and can be used repeatedly.