Cyclization of N-Butyl-4-pentenylaminyl:  Implications for the Cyclization of Alkenylaminyl Radicals

The utility of arenesulfenamides as aminyl radical precursors has been clearly demonstrated. The cyclization of N-butyl-4-pentenylaminyl is shown to be a slow and irreversible process that is accelerated significantly by small amounts of bis(tributyltin) oxide.

Saved in:
Bibliographic Details
Published inJournal of the American Chemical Society Vol. 118; no. 18; pp. 4276 - 4283
Main Authors Maxwell, Brendan J, Tsanaktsidis, John
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 08.05.1996
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
ALKENES
GENERATION
AMINYL RADICALS
PRECURSORS
SULFENAMIDES
ANODIC-OXIDATION
Online AccessGet full text

Cover

More Information
Summary:The utility of arenesulfenamides as aminyl radical precursors has been clearly demonstrated. The cyclization of N-butyl-4-pentenylaminyl is shown to be a slow and irreversible process that is accelerated significantly by small amounts of bis(tributyltin) oxide.
Bibliography:Abstract published in Advance ACS Abstracts, April 15, 1996.
ark:/67375/TPS-6BDXKJ7Q-T
istex:1176F06A84DC10EDA365632E4A78F0AC510320D0
ISSN:0002-7863
1520-5126
DOI:10.1021/ja953720s