Tough and Healable Elastomers via Dynamic Integrated Moiety Comprising Covalent and Noncovalent Interactions

Elastomers that combined excellent mechanical performance and healability are essential to the advancement of stretchable electronics. However, the strength and toughness of healable elastomers tend to be mutually exclusive. Herein, a new strategy of the dynamic integrated moiety is developed to con...

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Bibliographic Details
Published inChemistry of materials Vol. 34; no. 7; pp. 2981 - 2988
Main Authors Gao, Xiaoyu, Fan, Wenru, Zhu, Wei, Jiuwei, Gao, Zhang, Pengfang, Wang, Chen, Wang, Xuewen, Xia, Hesheng, Wang, Zhenhua, Huang, Wei
Format Journal Article
LanguageEnglish
Published American Chemical Society 12.04.2022
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Summary:Elastomers that combined excellent mechanical performance and healability are essential to the advancement of stretchable electronics. However, the strength and toughness of healable elastomers tend to be mutually exclusive. Herein, a new strategy of the dynamic integrated moiety is developed to construct covalent and noncovalent cross-linked polyurethane (CNPU) elastomers. The covalent and noncovalent interactions synergistically enhance the overall mechanical properties of polyurethane elastomers such as tensile strength (48.8 MPa), toughness (282.9 MJ·m–3), stretchability (1740%), and healing efficiency (116%). Finally, elastic conductive wires are fabricated with high load capacity, stable electrical conductivity under static/dynamic stretching, and robust healability to demonstrate the potential use of CNPU elastomers in stretchable electronics.
ISSN:0897-4756
1520-5002
DOI:10.1021/acs.chemmater.1c03813