Thermodynamic Two-Site Surface Reaction Model for Predicting Munition Constituent Reduction Kinetics with Iron (Oxyhydr)oxides

• Published in: Environmental science & technology Vol. 57; no. 33; pp. 12411 - 12420
• Main Authors: Hickey, Kevin P., Cardenas-Hernandez, Paula, Di Toro, Dominic M., Allen, Herbert E., Carbonaro, Richard F., Chiu, Pei C.
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 22.08.2023
• Subjects: Acidity; Binding sites; Goethite; Hematite; Iron constituents; Iron oxides; Kinetics; Nitro compounds; Occurrence, Fate, and Transport of Aquatic and Terrestrial Contaminants; Oxides; Rate constants; Reaction kinetics; Redox properties; Reducing agents; Soil contamination; Soil remediation; Surface reactions; Thermodynamics; Titration; adsorption; double layer; ferrous iron; munition constituents; rate constants; complexation; reduction
• ISSN: 0013-936X; 1520-5851
• DOI: 10.1021/acs.est.3c02651

Iron (oxyhydr)­oxides comprise a significant portion of the redox-active fraction of soils and are key reductants for remediation of sites contaminated with munition constituents (MCs). Previous studies of MC reduction kinetics with iron oxides have focused on the concentration of sorbed Fe­(II) as a key parameter. To build a reaction kinetic model, it is necessary to predict the concentration of sorbed Fe­(II) as a function of system conditions and the redox state. A thermodynamic framework is formulated that includes a generalized double-layer model that utilizes surface acidity and surface complexation reactions to predict sorbed Fe­(II) concentrations that are used for fitting MC reduction kinetics. Monodentate- and bidentate Fe­(II)-binding sites are used with individual oxide sorption characteristics determined through data fitting. Results with four oxides (goethite, hematite, lepidocrocite, and ferrihydrite) and four nitro compounds (NB, CN-NB, Cl-NB, and NTO) from six separate studies have shown good agreement when comparing observed and predicted surface area-normalized rate constants. While both site types are required to reproduce the experimental redox titration, only the monodentate site concentration controls the MC reaction kinetics. This model represents a significant step toward predicting the timescales of MC degradation in the subsurface.