Observation of a reaction front in the bulk catalytic hydrogenation of a polyolefin

Polyolefins can be hydrogenated to good conversions under moderate conditions in the absence of added solvent by using the crabtree catalyst. This paper presents the results of the behavior of the reaction front during the hydrogenation and the nature of the interface produced in partially hydrogena...

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Bibliographic Details
Published inMacromolecules Vol. 25; no. 22; pp. 6066 - 6068
Main Authors Gilliom, Laura R, Honnell, Kevin G
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.10.1992
Subjects
Applied sciences
Chemical modifications
Chemical reactions and properties
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Interface structure
Chemical modification
Catalytic reaction
Gas solid reaction
SBS
Solid solid interface
Time curve
Experimental study
Hydrogenation
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Summary:Polyolefins can be hydrogenated to good conversions under moderate conditions in the absence of added solvent by using the crabtree catalyst. This paper presents the results of the behavior of the reaction front during the hydrogenation and the nature of the interface produced in partially hydrogenated pellets.
Bibliography:ark:/67375/TPS-6NV3VDH4-Q
istex:1265F11156B48CED477AA654A7A4A90230AAD808
ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0024-9297
1520-5835
DOI:10.1021/ma00048a034