Redox Noninnocent Nature of Acridine-Based Pincer Complexes of 3d Metals and C–C Bond Formation

Acridine-based PNP pincer complexes have been previously utilized for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, we report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. We also report here the no...

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Published inOrganometallics Vol. 39; no. 2; pp. 279 - 285
Main Authors Daw, Prosenjit, Kumar, Amit, Oren, Dror, Espinosa-Jalapa, Noel Angel, Srimani, Dipankar, Diskin-Posner, Yael, Leitus, Gregory, Shimon, Linda J. W, Carmieli, Raanan, Ben-David, Yehoshoa, Milstein, David
Format Journal Article
LanguageEnglish
Published American Chemical Society 27.01.2020
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Summary:Acridine-based PNP pincer complexes have been previously utilized for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, we report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. We also report here the noninnocent redox nature of these complexes that results in the dimerization of pincer complexes by forming a C–C bond at the C9 position of the acridine ring.
ISSN:0276-7333
1520-6041
DOI:10.1021/acs.organomet.9b00607