N-Heterocyclic Pincer Dicarbene Complexes of Iron(II):  C-2 and C-5 Metalated Carbenes on the Same Metal Center

• Published in: Organometallics Vol. 23; no. 2; pp. 166 - 168
• Main Authors: Danopoulos, Andreas A, Tsoureas, Nikolaos, Wright, Joseph A, Light, Mark E
• Format: Journal Article
• Language: English
• Published: American Chemical Society 19.01.2004
• ISSN: 0276-7333; 1520-6041
• DOI: 10.1021/om0341911

Six- and five-coordinate Fe(II) complexes with the pincer ligand 2,6-bis(imidazolylidene)pyridine (C−N−C), [(C−N−C)Fe(MeCN)3][BPh4]2 and [(C−N−C)FeBr2], respectively, were synthesized. Substitution of tmeda in [FeCl2(tmeda)]2 by C−N−C gave the six-coordinate {[Fe(C−N−C)(C−N−C*)][FeCl4]}, in which one of the pincer ligands is bound to the metal via the 2- and 5-imidazole carbons.