Activation and Reactivity of (NHC)Pd(allyl)Cl (NHC = N-Heterocyclic Carbene) Complexes in Cross-Coupling Reactions

Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.

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Bibliographic Details
Published inOrganometallics Vol. 21; no. 25; pp. 5470 - 5472
Main Authors Viciu, Mihai S, Germaneau, Romain F, Navarro-Fernandez, Oscar, Stevens, Edwin D, Nolan, Steven P
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 09.12.2002
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
SYSTEM
IODIDES
KETONES
ALPHA-ARYLATION
ARYL HALIDES
CHLORIDES
CHEMISTRY
BROMIDES
PALLADIUM-CATALYZED AMINATION
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Summary:Mononuclear palladium-allyl complexes bearing one N-heterocyclic carbene (NHC) ligand have been synthesized. These complexes offer a straightforward entryway into a number of catalytic cycles by simple action of a base.
Bibliography:istex:2BEE4863E6501DC44C7A7FCB616898DE103CBF7B
ark:/67375/TPS-H0NC5V51-L
ISSN:0276-7333
1520-6041
DOI:10.1021/om020804i