Behavior of Multiclass Pesticide Residue Concentrations during the Transformation from Rose Petals to Rose Absolute

• Published in: Journal of agricultural and food chemistry Vol. 63; no. 20; pp. 4922 - 4932
• Main Authors: Tascone, Oriane, Fillâtre, Yoann, Roy, Céline, Meierhenrich, Uwe J
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 27.05.2015; American Chemical Society, Books and Journals Division
• Subjects: chlorpyrifos; concrete; corolla; fenamiphos; fenthion; Flowers - chemistry; gas chromatography; Gas Chromatography-Mass Spectrometry; methidathion; Perfume - analysis; pesticide residues; Pesticide Residues - chemistry; phorate; Rosa; Rosa - chemistry; tandem mass spectrometry; Turkey (country); concrete; dispersive SPE; rose flowers; pesticides; absolute; aroma and perfume chemistry; cosmetic industry; natural extracts
• ISSN: 0021-8561; 1520-5118
• DOI: 10.1021/acs.jafc.5b00985

This study investigates the concentrations of 54 multiclass pesticides during the transformation processes from rose petal to concrete and absolute using roses spiked with pesticides as a model. The concentrations of the pesticides were followed during the process of transforming the spiked rose flowers from an organic field into concrete and then into absolute. The rose flowers, the concrete, and the absolute, as well as their transformation intermediates, were analyzed for pesticide content using gas chromatography/tandem mass spectrometry. We observed that all the pesticides were extracted and concentrated in the absolute, with the exception of three molecules: fenthion, fenamiphos, and phorate. Typical pesticides were found to be concentrated by a factor of 100–300 from the rose flowers to the rose absolute. The observed effect of pesticide enrichment was also studied in roses and their extracts from four classically phytosanitary treated fields. Seventeen pesticides were detected in at least one of the extracts. Like the case for the spiked samples in our model, the pesticides present in the rose flowers from Turkey were concentrated in the absolute. Two pesticides, methidathion and chlorpyrifos, were quantified in the rose flowers at approximately 0.01 and 0.01–0.05 mg kg–1, respectively, depending on the treated field. The concentrations determined for the corresponding rose absolutes were 4.7 mg kg–1 for methidathion and 0.65–27.25 mg kg–1 for chlorpyrifos.