Highly Tunable Heterometallic Frameworks Constructed from Paddle-Wheel Units and Metalloporphyrins

Seven new heterometallic frameworks have been synthesized with specific control over the metallic composition of each structure. Using Mn, Fe, Ni, V, and Pt metallated tetra-(4-carboxyphenyl)porphine (MTCPP) metalloligands and Zn and Co paddle-wheel building units, two series of heterometallic frame...

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Bibliographic Details
Published inCrystal growth & design Vol. 9; no. 4; pp. 1960 - 1965
Main Authors Barron, Paul M, Son, Hyun-Tak, Hu, Chunhua, Choe, Wonyoung
Format Journal Article
LanguageEnglish
Published Washington,DC American Chemical Society 01.04.2009
Subjects
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Metal organic framework
Organometallic compounds
Iron
Nickel
Metalloporphyrin
Topology
Crystal structure
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Summary:Seven new heterometallic frameworks have been synthesized with specific control over the metallic composition of each structure. Using Mn, Fe, Ni, V, and Pt metallated tetra-(4-carboxyphenyl)porphine (MTCPP) metalloligands and Zn and Co paddle-wheel building units, two series of heterometallic frameworks are assembled that maintain topology with changing metal composition.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg801267m