Gold(I) Complexes with Hydrogen-Bond Supported Heterocyclic Carbenes as Active Catalysts in Reactions of 1,6-Enynes
Complexes [AuCl{C(NHR)(NHPy-2)}] (Py-2 = 2-pyridyl; R = Me, t Bu, n Bu, i Pr, n heptyl) have been prepared in a modular way from [AuCl(CNPy-2)]. The carbene moiety has a hydrogen-bond supported heterocyclic structure similar to the nitrogen heterocyclic carbenes in the solid state, and in CH2Cl2 or...
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Published in | Inorganic chemistry Vol. 47; no. 23; pp. 11391 - 11397 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
01.12.2008
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Online Access | Get full text |
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Summary: | Complexes [AuCl{C(NHR)(NHPy-2)}] (Py-2 = 2-pyridyl; R = Me, t Bu, n Bu, i Pr, n heptyl) have been prepared in a modular way from [AuCl(CNPy-2)]. The carbene moiety has a hydrogen-bond supported heterocyclic structure similar to the nitrogen heterocyclic carbenes in the solid state, and in CH2Cl2 or acetone solution, which is open in the presence of MeOH. The compounds are good catalysts for the skeletal rearrangement of enynes, and for the methoxycyclization of enynes. In contrast, the complexes [AuCl{C(NHR)(NHPy-4)}] are scarcely active due to the blocking effect of the coordination position required for the catalysis by the nitrogen of the NHPy-4 group. |
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Bibliography: | This material is available free of charge via the Internet at http://pubs.acs.org. ark:/67375/TPS-9FZRH4JH-8 istex:0FC0128BC87D8B60C87B6F20F696B9277544C74D ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0020-1669 1520-510X |
DOI: | 10.1021/ic801446v |