Synthesis and Characterization of Heterobimetallic Iridium–Aluminum and Rhodium–Aluminum Complexes

We demonstrate the synthesis and characterization of a new class of late-transition-metal–aluminum heterobimetallic complexes via a novel synthetic pathway. Complexes of this type are exceedingly rare. Joint experimental and theoretical data sheds light on the electronic effect of ligands containing...

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Published inInorganic chemistry Vol. 57; no. 3; pp. 1148 - 1157
Main Authors Brewster, Timothy P, Nguyen, Tan H, Li, Zhongjing, Eckenhoff, William T, Schley, Nathan D, DeYonker, Nathan J
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 05.02.2018
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Summary:We demonstrate the synthesis and characterization of a new class of late-transition-metal–aluminum heterobimetallic complexes via a novel synthetic pathway. Complexes of this type are exceedingly rare. Joint experimental and theoretical data sheds light on the electronic effect of ligands containing aluminum moieties on late-transition-metal complexes.
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ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.7b02601