Three-Dimensional Polyoxometalate Organic Frameworks with One-Dimensional Channels Constructed by Multiple Helical Chains Based on 22-Core Ln/Mn/Mo Clusters for Proton Conduction

Two unique 22-core sandwich {[Mn6Mo6O37]­Ln3[MnMo6O24]} (Ln = La or Pr) units have been assembled, featuring an undisclosed {Mn6Mo6} cluster. This assembly is subsequently integrated into two three-dimensional polyoxometalate organic frameworks, which exhibit one-dimensional hydrophilic hexagonal ch...

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Published inInorganic chemistry Vol. 63; no. 8; pp. 3637 - 3641
Main Authors Li, Ya-Xin, Liu, Shuang, Fan, Yan-Hua, Andra, Swetha, Dang, Dong-Bin, Li, Ya-Min, Bai, Yan
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 26.02.2024
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Summary:Two unique 22-core sandwich {[Mn6Mo6O37]­Ln3[MnMo6O24]} (Ln = La or Pr) units have been assembled, featuring an undisclosed {Mn6Mo6} cluster. This assembly is subsequently integrated into two three-dimensional polyoxometalate organic frameworks, which exhibit one-dimensional hydrophilic hexagonal channels formed by six intertwined 63 helical chains, leading to effective proton conduction primarily facilitated by an abundance of water molecules within the channels.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.3c03678