Straightforward Synthesis of Single-Crystalline and Redox-Active Cr(II)-carboxylate MOFs

We report on a facile and environmentally friendly synthetic approach for single-crystalline chromium­(II) carboxylate metal–organic frameworks (i.e., Cr3(BTC)2·3H2O (1) and Cr­(hfipbb)·H2O (2) at room temperature in water. Both MOFs can be easily dehydrated, affording single-crystalline materials w...

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Published inInorganic chemistry Vol. 57; no. 9; pp. 4803 - 4806
Main Authors Leszczyński, Michał K, Kornowicz, Arkadiusz, Prochowicz, Daniel, Justyniak, Iwona, Noworyta, Krzysztof, Lewiński, Janusz
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 07.05.2018
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Summary:We report on a facile and environmentally friendly synthetic approach for single-crystalline chromium­(II) carboxylate metal–organic frameworks (i.e., Cr3(BTC)2·3H2O (1) and Cr­(hfipbb)·H2O (2) at room temperature in water. Both MOFs can be easily dehydrated, affording single-crystalline materials with open Cr­(II) sites. In addition, the redox activity and porosity of the resulting Cr­(II) MOFs were examined.
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ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.8b00395