Palladium–Schiff Base Complexes Encapsulated in Zeolite‑Y Host: Functionality Controlled by the Structure of a Guest Complex

• Published in: Inorganic chemistry Vol. 58; no. 2; pp. 1527 - 1540
• Main Authors: Kumari, Susheela, Maddipoti, Karthik, Das, Bidisa, Ray, Saumi
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 22.01.2019
• ISSN: 0020-1669; 1520-510X; 1520-510X
• DOI: 10.1021/acs.inorgchem.8b03031

A series of palladium complexes of tetradendate Schiff base ligands L1 (N,N′-bis­(salicylidene)­phenylene-1,3-diamine) and its derivatives L2 and L3 have been synthesized by using the “flexible ligand method” within the supercage of zeolite-Y. These complexes in both their free and encapsulated states have been thoroughly characterized with the help of different characterization tools such as XRD, SEM-EDS, BET, thermal analysis, XPS, IR, and UV–vis spectroscopic studies. All these encapsulated complexes are identified with a dramatic red shift of the d–d transition in their electronic spectra when compared with their free states. Theoretical as well as experimental studies together suggest a substantial modification of the structural parameters of square planar Pd­(II)–Schiff base complexes upon encapsulation within the supercage of zeolite-Y. Encapsulated complexes are also subject to show modified catalytic activities toward the Heck reaction. These heterogeneous catalysts can easily be separated from the reaction mixture and reused.