Synthesis of Macrocyclic Cage Compounds by Diamine−Dihalide One-Step Coupling Reaction

Macropolycyclic cage compounds were synthesized by a direct reaction between diamines and bis(bromomethyl) compounds. The procedure for constructing the polycyclic cage structure is simple and straightforward. The macropolycyclic compounds obtainable from this cyclization procedure are three-dimensi...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 65; no. 12; pp. 3708 - 3715
Main Authors Kon, Noriyoshi, Takemura, Hiroyuki, Otsuka, Kazuhiro, Tanoue, Kiyoshi, Nakashima, Sachiko, Yasutake, Mikio, Tani, Keita, Kimoto, Junko, Shinmyozu, Teruo, Inazu, Takahiko
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 16.06.2000
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
MACROBICYCLIC LIGANDS
RECOGNITION
PYRIDINE
COMPLEXES
INCLUSION
SUBUNITS
CRYPTANDS
BIPYRIDINE
KYUPHANE
MOLECULES
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Summary:Macropolycyclic cage compounds were synthesized by a direct reaction between diamines and bis(bromomethyl) compounds. The procedure for constructing the polycyclic cage structure is simple and straightforward. The macropolycyclic compounds obtainable from this cyclization procedure are three-dimensional cage compounds, and any other isomers were not obtained except for two examples. Benzene, pyridine, and aliphatic units could be introduced into the cage structure. The macrocycles that have strong cation affinity were obtained as their potassium complexes.
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ark:/67375/TPS-BWV34SDN-C
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ISSN:0022-3263
1520-6904
DOI:10.1021/jo991911y