Luminescent Thermochromism and White-Light Emission of a 3D [Ag4Br6] Cluster-Based Coordination Framework with Both Adamantane-like Node and Linker

Herein, we report a dia-type metal–organic hybrid network based on the [Ag4Br6] clusters and hexamethylenetetramine molecules wherein both the inorganic nodes and organic linkers feature adamantane-like geometry with a T d symmetry. The silver bromine complex presents a dual emission and exhibits an...

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Published inInorganic chemistry Vol. 60; no. 7; pp. 4375 - 4379
Main Authors Xue, Zhen-Zhen, Meng, Xiang-Dong, Li, Xin-Yu, Han, Song-De, Pan, Jie, Wang, Guo-Ming
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 05.04.2021
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Summary:Herein, we report a dia-type metal–organic hybrid network based on the [Ag4Br6] clusters and hexamethylenetetramine molecules wherein both the inorganic nodes and organic linkers feature adamantane-like geometry with a T d symmetry. The silver bromine complex presents a dual emission and exhibits an interesting luminescent thermochromism behavior. Remarkably, white-light emission can be readily realized through variation of the temperature. In addition, the title compound is expected to be competent as a luminescent thermometer for temperature identification.
Bibliography:ObjectType-Article-1
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content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.1c00280