Molecular Iodine Interactions with Fe, Ni, Cr, and Stainless Steel Alloys

• Published in: Industrial & engineering chemistry research Vol. 60; no. 6; pp. 2447 - 2454
• Main Authors: Beck, Chelsie L, Riley, Brian J, Chong, Saehwa, Smith, Nathaniel, Seiner, Derrick R, Seiner, Brienne N, Engelhard, Mark H, Clark, Sue B
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 17.02.2021; American Chemical Society (ACS)
• Subjects: atmospheric chemistry; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; iodine; layers; Materials and Interfaces; metals; oxides
• ISSN: 0888-5885; 1520-5045
• DOI: 10.1021/acs.iecr.0c04590

The adsorption behavior of molecular iodine is important for understanding the spread of radioiodine in a nuclear accident. Prior experiments indicate that, in addition to the interaction with Fe, molecular iodine [i.e., I2(g)] also interacts with the next most abundant components of austenitic stainless steel (i.e., Ni, and Cr) at room temperature. In this study, we investigate iodine adsorption on Fe, Ni, and Cr while focusing on understanding the variables affecting adsorption as well as the iodine compounds that are formed during adsorption. Scanning electron microscopy and energy-dispersive X-ray spectroscopy were used to characterize the surfaces of exposed metal particles and aid in the understanding of the morphology and chemistry of iodine interactions with the substrates. Inductively coupled plasma optical emission spectroscopy was used to detect low levels of metal iodides and X-ray photoelectron spectroscopy was used to confirm the formation of the metal iodides. The role of environmental factors (e.g., humidity and oxygen content) for iodine adsorption on metal substrates is addressed. The individual metals demonstrated formation of metal iodides for Fe and Ni particles from interaction with I2(g). The formation of metal iodides may indicate the affinity of iodine for the respective metal. In this study, the iodine affinities ranked Fe > Ni > Cr as determined by the quantity of chemisorbed iodine. This trend is also supported by the distributions and proportions of metals in the corrosion product of the stainless steels. The exposures without oxygen and humidity indicate the potential of a multistep iodine adsorption process where iodine first attacks the oxide layer and then chemisorbs to the exposed metal.