Complexation of Lactate with Neodymium(III) and Europium(III) at Variable Temperatures: Studies by Potentiometry, Microcalorimetry, Optical Absorption, and Luminescence Spectroscopy

• Published in: Inorganic chemistry Vol. 49; no. 22; pp. 10598 - 10605
• Main Authors: Tian, Guoxin, Martin, Leigh R, Rao, Linfeng
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 15.11.2010
• ISSN: 0020-1669; 1520-510X
• DOI: 10.1021/ic101592h

The complexation of neodymium(III) and europium(III) with lactate was studied at variable temperatures by potentiometry, absorption spectrophotometry, luminescence spectroscopy, and microcalorimetry. The stability constants of three successive lactate complexes (ML2+, ML2 +, and ML3(aq), where M stands for Nd and Eu and L stands for lactate) at 10, 25, 40, 55, and 70 °C were determined. The enthalpies of complexation at 25 °C were determined by microcalorimetry. Thermodynamic data show that the complexation of trivalent lanthanides (Nd3+ and Eu3+) with lactate is exothermic and the complexation becomes weaker at higher temperatures. Results from optical absorption and luminescence spectroscopy suggest that the complexes are inner-sphere chelate complexes in which the protonated α-hydroxyl group of lactate participates in the complexation.