The Effect of Low-Molecular-Weight Poly(ethylene glycol) (PEG) Plasticizers on the Transport Properties of Lithium Fluorosulfonimide Ionic Melt Electrolytes

• Published in: The journal of physical chemistry. B Vol. 118; no. 19; pp. 5135 - 5143
• Main Authors: Geiculescu, Olt E, Hallac, Boutros B, Rajagopal, Rama V, Creager, Stephen E, DesMarteau, Darryl D, Borodin, Oleg, Smith, Grant D
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 15.05.2014
• Subjects: Computer simulation; Electrolytes; Glycols; Lithium; Mathematical models; Melts; Plasticizers; Polyethers; Viscosity
• ISSN: 1520-6106; 1520-5207
• DOI: 10.1021/jp500826c

The influence of low-molecular-weight poly(ethylene glycol) (PEG, M w ≈ 550 Da) plasticizers on the rheology and ion-transport properties of fluorosulfonimide-based polyether ionic melt (IM) electrolytes has been investigated experimentally and via molecular dynamics (MD) simulations. Addition of PEG plasticizer to samples of IM electrolytes caused a decrease in electrolyte viscosity coupled to an increase in ionic conductivity. MD simulations revealed that addition of plasticizer increased self-diffusion coefficients for both cations and anions with the plasticizer being the fastest diffusing species. Application of a VTF model to fit variable-temperature conductivity and fluidity data shows that plasticization decreases the apparent activation energy (E a) and pre-exponential factor A for ion transport and also for viscous flow. Increased ionic conductivity with plasticization is thought to reflect a combination of factors including lower viscosity and faster polyether chain segmental dynamics in the electrolyte, coupled with a change in the ion transport mechanism to favor ion solvation and transport by polyethers derived from the plasticizer. Current interrupt experiments with Li/electrolyte/Li cells revealed evidence for salt concentration polarization in electrolytes containing large amounts of plasticizer but not in electrolytes without added plasticizer.