Redox-Modulated Recognition of Tetrazines Using Thioureas

Reduced 1,2,4,5-tetrazines serve as two-point hydrogen-bonding acceptors for thiourea. This host−guest system does not exhibit significant binding in the neutral state, making the complex an electrochemical “on/off” switch.

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Bibliographic Details
Published inOrganic letters Vol. 9; no. 15; pp. 2835 - 2838
Main Authors Jordan, Brian J, Pollier, Michael A, Miller, Luke A, Tiernan, Christopher, Clavier, Gilles, Audebert, Pierre, Rotello, Vincent M
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 19.07.2007
Subjects
Chemical Sciences
or physical chemistry
Organic chemistry
Theoretical and
INTERPLAY
MODEL SYSTEMS
QUINONES
DEPENDENT RECEPTORS
MOLECULAR RECOGNITION
SPECTROSCOPIC PROPERTIES
CHEMISTRY
FLAVOENZYME ACTIVITY
ARYLUREAS
HETEROATOMS
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Summary:Reduced 1,2,4,5-tetrazines serve as two-point hydrogen-bonding acceptors for thiourea. This host−guest system does not exhibit significant binding in the neutral state, making the complex an electrochemical “on/off” switch.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol070981l