A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes

This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.

Saved in:
Bibliographic Details
Published inJournal of the American Chemical Society Vol. 129; no. 4; pp. 762 - 763
Main Authors Du, Haifeng, Zhao, Baoguo, Shi, Yian
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 31.01.2007
Amer Chemical Soc
Subjects
Catalysis
Chemistry
Chemistry, Multidisciplinary
Diamines - chemistry
Palladium - chemistry
Physical Sciences
Polyenes - chemistry
Science & Technology
Stereoisomerism
INTRAMOLECULAR DIAMINATION
ALKENES
AMINATION
ELECTROPHILIC DIAMINATION
1,2-DIAMINATION
Online AccessGet full text

Cover

More Information
Summary:This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.
Bibliography:ark:/67375/TPS-12TBJBND-5
istex:AB80E7722B5F068C4C1FA776BB97EECFD22A947A
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0680562