Arene Ruthenium Catalyst MCAT-53 for the Synthesis of Heterobiaryl Compounds in Water through Aromatic C–H Bond Activation
A new water friendly MCAT-53 [Ru2Cl2 (HCOO)3(p-cymene)] Na (sodium η-6-p-cymene dichloro diruthenium triformato complex) has been developed as a catalyst to effect aromatic C–H bond activation and C–C coupling reactions in water. Cross-coupling reactions were performed in DI/distilled water under ai...
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| Published in | Organic process research & development Vol. 22; no. 9; pp. 1119 - 1130 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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American Chemical Society
21.09.2018
Amer Chemical Soc |
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| Abstract | A new water friendly MCAT-53 [Ru2Cl2 (HCOO)3(p-cymene)] Na (sodium η-6-p-cymene dichloro diruthenium triformato complex) has been developed as a catalyst to effect aromatic C–H bond activation and C–C coupling reactions in water. Cross-coupling reactions were performed in DI/distilled water under air- and ligand-free conditions without further activation of the catalyst. Synthesis of an advanced intermediate of CETP inhibitor, Anacetrapib, in water has been demonstrated to give a single regioisomer using the MCAT-53 catalyst. |
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| AbstractList | A new water friendly MCAT-53 [Ru2Cl2 (HCOO)(3)(p-cymene)] Na (sodium eta-6-p-cymene dichloro diruthenium triformato complex) has been developed as a catalyst to effect aromatic C-H bond activation and C-C coupling reactions in water. Cross-coupling reactions were performed in DI/distilled water under air- and ligand-free conditions without further activation of the catalyst. Synthesis of an advanced intermediate of CETP inhibitor, Anacetrapib, in water has been demonstrated to give a single regioisomer using the MCAT-53 catalyst. A new water friendly MCAT-53 [Ru2Cl2 (HCOO)3(p-cymene)] Na (sodium η-6-p-cymene dichloro diruthenium triformato complex) has been developed as a catalyst to effect aromatic C–H bond activation and C–C coupling reactions in water. Cross-coupling reactions were performed in DI/distilled water under air- and ligand-free conditions without further activation of the catalyst. Synthesis of an advanced intermediate of CETP inhibitor, Anacetrapib, in water has been demonstrated to give a single regioisomer using the MCAT-53 catalyst. |
| Author | Mehta, Anita Chorghade, Mukund S Koohang, Ali Aiden Saha, Biswajit |
| AuthorAffiliation | Chicago Discovery Solutions LLC |
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| Author_xml | – sequence: 1 givenname: Anita orcidid: 0000-0002-0582-0871 surname: Mehta fullname: Mehta, Anita email: amehta@chicagodiscoverysolutions.com – sequence: 2 givenname: Biswajit surname: Saha fullname: Saha, Biswajit – sequence: 3 givenname: Ali Aiden surname: Koohang fullname: Koohang, Ali Aiden – sequence: 4 givenname: Mukund S surname: Chorghade fullname: Chorghade, Mukund S |
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| CitedBy_id | crossref_primary_10_1021_acssuschemeng_2c00873 crossref_primary_10_1002_ange_202306659 crossref_primary_10_2174_2213346106666191019120048 crossref_primary_10_1021_acscentsci_0c01413 crossref_primary_10_1002_anie_202306659 crossref_primary_10_1038_s43586_021_00041_2 |
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| Keywords | C−H activation C−C coupling ruthenium catalyst MCAT-53 C-C coupling FUNCTIONALIZATION CROSS-COUPLING REACTIONS CARBOXYLATE C-H activation PHENOLS REACTIVITY OLEFIN METATHESIS ARYL DIRECT ARYLATIONS |
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| Snippet | A new water friendly MCAT-53 [Ru2Cl2 (HCOO)3(p-cymene)] Na (sodium η-6-p-cymene dichloro diruthenium triformato complex) has been developed as a catalyst to... A new water friendly MCAT-53 [Ru2Cl2 (HCOO)(3)(p-cymene)] Na (sodium eta-6-p-cymene dichloro diruthenium triformato complex) has been developed as a catalyst... |
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| SubjectTerms | Chemistry Chemistry, Applied Chemistry, Organic Physical Sciences Science & Technology |
| Title | Arene Ruthenium Catalyst MCAT-53 for the Synthesis of Heterobiaryl Compounds in Water through Aromatic C–H Bond Activation |
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