Homozinniol, a New Phytotoxic Metabolite from Alternaria solani
A bioassay-guided fractionation of the phytotoxic crude extract of Alternaria solani resulted in the isolation of two phytotoxic metabolites identified as zinniol (1) and a new polyketide: homozinniol (2). A third metabolite, 6-[(3‘,3‘-dimethylallyl)oxy]-4-methoxy-5-methylphthalide (3) was also iso...
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Published in | Journal of agricultural and food chemistry Vol. 45; no. 1; pp. 282 - 285 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
WASHINGTON
American Chemical Society
01.01.1997
Amer Chemical Soc |
Subjects | |
Online Access | Get full text |
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Summary: | A bioassay-guided fractionation of the phytotoxic crude extract of Alternaria solani resulted in the isolation of two phytotoxic metabolites identified as zinniol (1) and a new polyketide: homozinniol (2). A third metabolite, 6-[(3‘,3‘-dimethylallyl)oxy]-4-methoxy-5-methylphthalide (3) was also isolated and identified. Structural assignment of the metabolites was based primarily on the analysis of their mass spectrometry and 1H NMR spectroscopy data. Keywords: Alternaria solani; Solanum tuberosum; Lycopersicon esculentum; phytotoxin; zinniol; homozinniol; polyketide; phthalide |
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Bibliography: | 1997062857 H20 ark:/67375/TPS-JM0RZ6SX-N istex:6F6E9D77C9E85BB69ACC942065410E4E062CCA42 Abstract published in Advance ACS Abstracts, November 15, 1996. |
ISSN: | 0021-8561 1520-5118 |
DOI: | 10.1021/jf960134p |