Adhesion of Particles with Sharp Edges to Air–Liquid Interfaces

• Published in: Langmuir Vol. 28; no. 30; pp. 11042 - 11047
• Main Authors: Ally, Javed, Kappl, Michael, Butt, Hans-Jürgen
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 31.07.2012
• Subjects: Air; Chemistry; Colloids - chemistry; Exact sciences and technology; General and physical chemistry; Solid-liquid interface; Surface physical chemistry; Surface Properties; Water - chemistry; Wettability; Water drop; Retraction; Force; Ions; Solid particle; Air; Contact angle; Adhesion; Contact line; Geometry; Particle; Liquid; Bubble; Wettability; Hysteresis; Interface
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la300539m

In order to study the effect of sharp edges on solid particle adhesion to air–liquid interfaces, spherical colloidal probes were modified with a circumferential cut by focused ion beam milling. The interaction of the modified particles with water drops and bubbles was studied using the colloidal probe technique. When the modified particles were brought into contact with air–liquid interfaces, the contact line was pinned at the edge of the cut. Contact hysteresis between the approach and retraction components of the measured force curves was eliminated. The contact angle at the edge takes a range of values within the limits defined by the Gibbs inequality. These limits determine the adhesion force. As such, the adhesion force is a function of the particle wettability and edge geometry.