Resonant Mixing Dynamic Nuclear Polarization

• Published in: The journal of physical chemistry letters Vol. 14; no. 31; pp. 7007 - 7013
• Main Authors: Quan, Yifan, Ouyang, Yifu, Mardini, Michael, Palani, Ravi Shankar, Banks, Daniel, Kempf, James, Wenckebach, W. Tom, Griffin, Robert G.
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 10.08.2023
• Subjects: Physical Insights into Chemistry, Catalysis, and Interfaces
• ISSN: 1948-7185; 1948-7185
• DOI: 10.1021/acs.jpclett.3c01869

We propose a mechanism for dynamic nuclear polarization that is different from the well-known Overhauser effect, solid effect, cross effect, and thermal mixing processes. We term it Resonant Mixing (RM), and we show that it arises from the evolution of the density matrix for a simple electron–nucleus coupled spin pair subject to weak microwave irradiation, the same interactions as the solid effect. However, the SE is optimal when the microwave field is off-resonance, whereas RM is optimal when the microwave field is on-resonance and involves the mixing of states by the microwave field together with the electron–nuclear coupling. Finally, we argue that this mechanism is responsible for the observed dispersive-shaped DNP field profile for trityl samples near the electron paramagnetic resonance center.