Synthesis of Diorganyl Selenides Mediated by Zinc in Ionic Liquid

A new approach for the synthesis of diorganyl selenides is described. By using economically attractive zinc dust in BMIM-BF4, a series of diorganyl selenides were efficiently achieved in excellent yields, under neutral reaction conditions. Compared to the usual organic solvents, BMIM-BF4 exhibited h...

Full description

Saved in:
Bibliographic Details
Published inJournal of organic chemistry Vol. 75; no. 11; pp. 3886 - 3889
Main Authors Narayanaperumal, Senthil, Alberto, Eduardo E, Gul, Kashif, Rodrigues, Oscar E. D, Braga, Antonio L
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 04.06.2010
Amer Chemical Soc
Subjects
Aliphatic compounds
Chemistry
Chemistry, Organic
Exact sciences and technology
Ionic Liquids - chemistry
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
Selenium - chemistry
Solvents
Zinc - chemistry
HYDROGEN
ORGANOSELENIUM
REAGENTS
SELENOCYSTEINE DERIVATIVES
DIPHENYL DISELENIDE
CATALYZED SYNTHESIS
IODIDE
EFFICIENT SYNTHESIS
CLEAVAGE
ALKYL-HALIDES
Organic selenide
Organic solvent
Neutral medium
Reuse
Transition metal
Chemical synthesis
Zinc
Ionic liquid
Successive reaction
Online AccessGet full text

Cover

More Information
Summary:A new approach for the synthesis of diorganyl selenides is described. By using economically attractive zinc dust in BMIM-BF4, a series of diorganyl selenides were efficiently achieved in excellent yields, under neutral reaction conditions. Compared to the usual organic solvents, BMIM-BF4 exhibited higher performance with the advantage to be reused up to five successive runs.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/jo100454m