Graft Copolymerization of Methyl Methacrylate onto Mercaptochitin and Some Properties of the Resulting Hybrid Materials

• Published in: Biomacromolecules Vol. 3; no. 1; pp. 147 - 152
• Main Authors: Kurita, Keisuke, Inoue, Masao, Harata, Manabu
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 01.01.2002
• Subjects: Animals; Cattle; Chitin - analogs & derivatives; Chitin - chemistry; Egg White; Hydrolysis; Methylmethacrylate - chemistry; Muramidase - metabolism; Polymers - chemistry; Spectrophotometry, Infrared; Temperature; Thermodynamics; Wettability
• ISSN: 1525-7797; 1526-4602
• DOI: 10.1021/bm0101320

The graft copolymerization of methyl methacrylate onto mercaptochitin and some properties of the resulting graft copolymers have been studied. Methyl methacrylate was efficiently graft copolymerized onto mercaptochitin in dimethyl sulfoxide, and the grafting percentage reached 1300% under appropriate conditions. Although the side-chain ester groups were resistant to aqueous alkali, hydrolysis could be achieved with a mixture of aqueous sodium hydroxide and dimethyl sulfoxide. Subsequent treatment with acetic anhydride in methanol transformed the sodium carboxylate groups into carboxyl groups. Although the graft copolymers exhibited an improved affinity for organic solvents, those having sodium carboxylate or carboxyl units were characterized by a much more enhanced solubility and were soluble in common solvents. The hygroscopic nature of chitin decreased with an increase in the grafting extent but increased significantly upon hydrolysis of the ester groups. The enzymatic degradability of the graft copolymers, as evaluated with lysozyme, was also dependent on the grafting extent and much higher than that of the original chitin. DSC measurements revealed the presence of a glass transition phenomenon, which could be ascribed to the poly(methyl methacrylate) side chain.