Shedding Light on the Moisture Stability of 3D/2D Hybrid Perovskite Heterojunction Thin Films
To increase the moisture stability of hybrid perovskite photovoltaics, a combination of three-dimensional (3D) and a thin layer of two-dimensional (2D) perovskite incorporating long-chained organic cations is often employed as photoabsorber. However, the detailed interaction between water and 3D/2D...
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Published in | ACS applied energy materials Vol. 2; no. 2; pp. 1011 - 1018 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
25.02.2019
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Subjects | |
Online Access | Get full text |
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Summary: | To increase the moisture stability of hybrid perovskite photovoltaics, a combination of three-dimensional (3D) and a thin layer of two-dimensional (2D) perovskite incorporating long-chained organic cations is often employed as photoabsorber. However, the detailed interaction between water and 3D/2D perovskite heterojunctions has not been elucidated yet. Using in situ neutron and X-ray scattering techniques, we reveal surprisingly strong water uptake into 3D/2D perovskite films despite the presence of hydrophobic bulky cations. Our results show rapid disproportionation of the initial 2D phase (number of layers, m = 5) in methylammonium lead iodide (MAPI)/2D films into lower m phases under humidity. Nevertheless, the 2D perovskite inhibits the irreversible PbI2 formation, which suggests that the suppression of I– and MA+ ion migration and consequently of MAI escape is related to the improved moisture stability of MAPI/2D perovskite films. In comparison, quadruple-cation perovskites including Rb+ exhibit poor stability toward phase segregation upon exposure to moisture regardless of the 2D perovskite layer. |
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ISSN: | 2574-0962 2574-0962 |
DOI: | 10.1021/acsaem.9b00005 |