The Kongsberg silver deposits, Norway: Ag-Hg-Sb mineralization and constraints for the formation of the deposits

• Published in: Mineralium deposita Vol. 53; no. 4; pp. 531 - 545
• Main Authors: Kotková, Jana, Kullerud, Kåre, Šrein, Vladimír, Drábek, Milan, Škoda, Radek
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.04.2018; Springer Nature B.V
• Subjects: Antimony; Arsenic; Arsenides; Bearing; Breakdown; Chalcopyrite; Cobalt; Crystals; Deposits; Earth and Environmental Science; Earth Sciences; Electron microprobe; Electron probe microanalysis; Fluids; Geology; Heating; Iron; Low temperature; Mercury; Microscopy; Mineral assemblages; Mineral Resources; Mineralization; Mineralogy; Minerals; Nickel; Pyrite; Silver; Solid solutions; Solutions; Sulfur; Sulphur; Kongsberg silver district; Ag-Hg-Sb relationships; Ni-Co-Fe sulfarsenides; Myrmekite; Ag-bearing sulfides
• ISSN: 0026-4598; 1432-1866
• DOI: 10.1007/s00126-017-0757-1

The Kongsberg silver district has been investigated by microscopy and electron microprobe analysis, focusing primarily on the Ag-Hg-Sb mineralization within the context of the updated mineral paragenesis. The earliest mineralization stage is represented by sulfides, including acanthite, and sulfosalts. Native silver formed initially through breakdown of early Ag-bearing phases and later through influx of additional Ag-bearing fluids and silver remobilization. The first two generations of native silver were separated in time by the formation of Ni-Co-Fe sulfarsenides and the monoarsenide niccolite along rims of silver crystals. The presence of As-free sulfosalts and the absence of di- and tri-arsenides suggest a lower arsenic/sulfur activity ratio for the Kongsberg deposits compared to other five-element deposits. Native silver shows binary Ag-Hg and Ag-Sb solid solutions, in contrast to the ternary Ag-Hg-Sb compositions typical for other deposits of similar type. Antimonial silver together with allargentum, dyscrasite, and pyrargyrite was documented exclusively from the northern area of the district. Elsewhere, the only Sb-bearing minerals are polybasite and tetrahedrite/freibergite. Hg-rich silver (up to 21 wt% Hg) has been documented only in the central-western area. Myrmekite of freibergite and chalcopyrite reflects exsolution from an original Ag-poor tetrahedrite upon cooling, while myrmekite of pyrite and silver, forming through breakdown of low-temperature phases (argentopyrite or lenaite) upon heating, characterizes the Kongsberg silver district. Based on the stabilities of minerals and mineral assemblages, the formation of the silver mineralization can be constrained to temperatures between 180 and 250 °C.