Strong Plasmon-Phonon Splitting and Hybridization in 2D Materials Revealed through a Self-Energy Approach

• Published in: ACS photonics Vol. 4; no. 11; pp. 2908 - 2915
• Main Authors: Settnes, Mikkel, Saavedra, J. R. M, Thygesen, Kristian S, Jauho, Antti-Pekka, García de Abajo, F. Javier, Mortensen, N. Asger
• Format: Journal Article
• Language: English
• Published: American Chemical Society 15.11.2017
• Subjects: nanophotonics; molecular plasmonics; many-body interactions; quantum plasmonics; 2D materials; graphene plasmons
• ISSN: 2330-4022; 2330-4022
• DOI: 10.1021/acsphotonics.7b00928

We reveal new aspects of the interaction between plasmons and phonons in 2D materials that go beyond a mere shift and increase in plasmon width due to coupling to either intrinsic vibrational modes of the material or phonons in a supporting substrate. More precisely, we predict strong plasmon splitting due to this coupling, resulting in a characteristic avoided crossing scheme. We base our results on a computationally efficient approach consisting in including many-body interactions through the electron self-energy. We specify this formalism for a description of plasmons based upon a tight-binding electron Hamiltonian combined with the random-phase approximation. This approach is valid provided vertex corrections can be neglected, as is the case in conventional plasmon-supporting metals and Dirac-Fermion systems. We illustrate our method by evaluating plasmonic spectra of doped graphene nanotriangles with varied size, where we predict remarkable peak splittings and other radical modifications in the spectra due to plasmon interactions with intrinsic optical phonons. Our method is equally applicable to other 2D materials and provides a simple approach for investigating coupling of plasmons to phonons, excitons, and other excitations in hybrid thin nanostructures.