High-Open-Circuit-Voltage Solar Cells Based on Bright Mixed-Halide CsPbBrI2 Perovskite Nanocrystals Synthesized under Ambient Air Conditions
Lead halide perovskite nanocrystals (NCs) are currently emerging as one of the most interesting solution-processed semiconductors because they possess high photoluminescence quantum yield (PLQY) and color tunability through anion exchange reactions or quantum confinement. Here, we show efficient sol...
Saved in:
Published in | Journal of physical chemistry. C Vol. 122; no. 14; pp. 7621 - 7626 |
---|---|
Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
12.04.2018
|
Online Access | Get full text |
Cover
Loading…
Summary: | Lead halide perovskite nanocrystals (NCs) are currently emerging as one of the most interesting solution-processed semiconductors because they possess high photoluminescence quantum yield (PLQY) and color tunability through anion exchange reactions or quantum confinement. Here, we show efficient solar cells based on mixed-halide (CsPbBrI2) NCs obtained via anion exchange reactions under ambient conditions. We performed anion exchange reactions in concentrated NC solutions with I–, thus inducing a PL red shift up to 676 nm and obtaining a high PLQY in film (65%). Solar cell devices operating in the wavelength range 350–660 nm were fabricated in air with two different deposition methods. The solar cells display a photoconversion efficiency of 5.3% and open circuit voltage (V oc) up to 1.31 V, among the highest reported for perovskite-based solar cells with band gap below 2 eV, clearly demonstrating the potential of this material. |
---|---|
ISSN: | 1932-7447 1932-7455 |
DOI: | 10.1021/acs.jpcc.8b01264 |