Developments in the Catalytic Asymmetric Synthesis of Agrochemicals and Their Synthetic Importance
Catalytic asymmetric synthesis has become an essential tool for the enantioselective synthesis of pharmaceuticals, natural products, and agrochemicals (mainly fungicides, herbicides, insecticides, and pheromones). With continuous growing interest in both modern agricultural chemistry and catalytic a...
Saved in:
| Published in | Journal of agricultural and food chemistry Vol. 69; no. 49; pp. 14761 - 14780 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Chemical Society
15.12.2021
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Catalytic asymmetric synthesis has become an essential tool for the enantioselective synthesis of pharmaceuticals, natural products, and agrochemicals (mainly fungicides, herbicides, insecticides, and pheromones). With continuous growing interest in both modern agricultural chemistry and catalytic asymmetric synthesis chemistry, this review provides a comprehensive overview of some earlier reports as well as the recent successful applications of various catalytic asymmetric syntheses methodologies, such as enantioselective hydroformylation, enantioselective hydrogenation, asymmetric Sharpless epoxidation and dihydroxylation, asymmetric cyclopropanation or isomerization, organocatalyzed asymmetric synthesis, and so forth, which have been used as key steps in the preparation of chiral agrochemicals (on R&D, piloting, and commercial scales). Chiral agrochemicals can also lead the new generation of such chemicals having specific and novel modes of action for achieving sustainable crop protection and production. Some perspectives and challenges for these catalytic asymmetric methodologies in the synthesis of chiral agrochemicals are also briefly discussed in the final section of the manuscript. This review will provide the insight regarding understanding, development, and evaluation of catalytic asymmetric systems for the synthesis of chiral agrochemicals among the agrochemists. |
|---|---|
| AbstractList | Catalytic asymmetric synthesis has become an essential tool for the enantioselective synthesis of pharmaceuticals, natural products, and agrochemicals (mainly fungicides, herbicides, insecticides, and pheromones). With continuous growing interest in both modern agricultural chemistry and catalytic asymmetric synthesis chemistry, this review provides a comprehensive overview of some earlier reports as well as the recent successful applications of various catalytic asymmetric syntheses methodologies, such as enantioselective hydroformylation, enantioselective hydrogenation, asymmetric Sharpless epoxidation and dihydroxylation, asymmetric cyclopropanation or isomerization, organocatalyzed asymmetric synthesis, and so forth, which have been used as key steps in the preparation of chiral agrochemicals (on R&D, piloting, and commercial scales). Chiral agrochemicals can also lead the new generation of such chemicals having specific and novel modes of action for achieving sustainable crop protection and production. Some perspectives and challenges for these catalytic asymmetric methodologies in the synthesis of chiral agrochemicals are also briefly discussed in the final section of the manuscript. This review will provide the insight regarding understanding, development, and evaluation of catalytic asymmetric systems for the synthesis of chiral agrochemicals among the agrochemists. |
| Author | Paniraj, Alilugatta Sheshagiri Rao Sharma, Sandeep Kumar Tambe, Yashwant Bhikaji |
| Author_xml | – sequence: 1 givenname: Sandeep Kumar orcidid: 0000-0002-7815-9607 surname: Sharma fullname: Sharma, Sandeep Kumar email: sandeep.sharma@rallis.com – sequence: 2 givenname: Alilugatta Sheshagiri Rao surname: Paniraj fullname: Paniraj, Alilugatta Sheshagiri Rao – sequence: 3 givenname: Yashwant Bhikaji surname: Tambe fullname: Tambe, Yashwant Bhikaji |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/34847666$$D View this record in MEDLINE/PubMed |
| BookMark | eNp1kD1PwzAQhi1URD9gZ0IZGUg523E-xqp8VarEQJkjx7nQVIkd7BSp_x6XBjamO-me95XumZKRNhoJuaYwp8DovVRuvpOVmlMFQgh-RiZUMAgFpemITMAzYSpiOiZT53YAkIoELsiYR2mUxHE8IcUDfmFjuhZ174JaB_0Wg6XsZXPoaxUs3KFtsbd-fTtof3O1C0wVLD6sUVtsayUbF0hdBpst1naAjslV2xnbS63wkpxXnsKrYc7I-9PjZvkSrl-fV8vFOpScx32YiajiIFRcSARWJDIFCqLkhSoqKirJuMwSJSArY55EUcl4UkTUP53xSmIm-Yzcnno7az736Pq8rZ3CppEazd7lLAbBWJIx7lE4ocoa5yxWeWfrVtpDTiE_ms292fxoNh_M-sjN0L4vWiz_Ar8qPXB3An6iZm-1f_b_vm-Uh4cz |
| CitedBy_id | crossref_primary_10_1002_slct_202300204 crossref_primary_10_1016_j_eurpolymj_2023_112275 crossref_primary_10_1016_j_ccr_2022_214922 crossref_primary_10_1051_e3sconf_202450501040 crossref_primary_10_1002_asia_202300912 crossref_primary_10_1021_acsorginorgau_2c00009 crossref_primary_10_1002_biot_202300027 crossref_primary_10_1002_tcr_202300300 crossref_primary_10_1007_s10661_024_12310_0 crossref_primary_10_1039_D2GC00655C crossref_primary_10_1002_cjoc_202300384 crossref_primary_10_1016_j_tchem_2022_100027 crossref_primary_10_3390_catal12070789 |
| Cites_doi | 10.1002/9783527619382.ch34 10.1016/j.envpol.2020.116269 10.7164/antibiotics.55.660 10.1021/ol200983s 10.1016/S0957-4166(99)00082-8 10.1016/j.envpol.2010.03.014 10.1016/S1381-1169(98)00398-7 10.1021/cr0684016 10.1021/acs.orglett.6b00748 10.1016/j.tetasy.2005.01.033 10.1021/op050166q 10.1016/j.jpba.2017.08.011 10.1021/acscatal.5b02846 10.1002/anie.199111933 10.1016/j.scitotenv.2020.141600 10.1002/(SICI)1096-9063(199601)46:1<3::AID-PS337>3.0.CO;2-J 10.1134/S1070428016050250 10.1021/acs.jafc.0c04163 10.1007/BF00394580 10.1073/pnas.86.4.1421 10.1016/S0040-4039(00)79002-2 10.1021/jacs.6b10690 10.1021/cr0100188 10.1039/c0gc00788a 10.1021/cr400037u 10.1016/S0957-4166(99)00482-6 10.1080/00397910903395243 10.1126/science.259.5094.479 10.1021/np000597w 10.1016/S0040-4020(01)87778-4 10.1039/c3cc44122a 10.1021/acs.accounts.7b00007 10.1002/(SICI)1521-3773(20000417)39:8<1428::AID-ANIE1428>3.0.CO;2-K 10.1002/anie.200300599 10.1021/ol006976y 10.1016/S0040-4039(00)73251-5 10.1016/S0040-4020(01)86523-6 10.6023/cjoc201903044 10.3390/molecules24061023 10.1351/pac200173010103 10.1007/s41061-016-0032-4 10.1016/j.tetasy.2015.03.006 10.1351/pac199769061335 10.1021/jacs.7b07188 10.1016/j.crci.2007.01.003 10.1002/cjoc.201100482 10.1021/ja00253a051 10.1016/S0957-4166(03)00519-6 10.1016/j.molcata.2004.09.053 10.1016/j.tetasy.2009.10.030 10.1002/1099-0690(200103)2001:6<1143::AID-EJOC1143>3.0.CO;2-O 10.1021/acs.oprd.9b00466 10.59566/IJBS.2006.2085 10.1002/anie.202006648 10.3390/molecules15021041 10.1016/S0926-860X(01)00801-8 10.1515/znb-1982-0411 10.1080/00304940903507788 10.1039/C6QO00641H 10.1002/adsc.200390000 10.1021/ja00185a050 10.1021/tx500481n 10.1017/S0890037X00033935 10.1002/(SICI)1096-9063(1998110)54:3<302::AID-PS831>3.0.CO;2-3 10.1016/j.tet.2008.04.079 10.1021/cr100218m 10.1016/0040-4039(95)01769-E 10.1021/np0200865 10.1002/anie.200500784 10.1016/S0957-4166(00)80506-6 10.1023/A:1019164928084 10.15227/orgsyn.073.0001 10.1016/j.tetasy.2017.07.004 10.1016/0957-4166(95)00178-R 10.1016/S0040-4039(00)78093-2 10.1016/S0040-4039(00)60957-7 10.1039/C39950002391 10.1023/A:1005447922939 10.1155/2014/402860 10.1002/chem.201604564 10.1016/0040-4039(96)01589-4 10.1021/ar7000809 10.1055/s-1986-31489 10.1021/cr200073d 10.1055/s-2001-18074 10.1039/a907396e 10.3390/catal9100802 10.1021/jo00005a024 10.1016/S0040-4039(00)61433-8 10.1021/ja106674n 10.1055/s-0033-1340838 10.1016/j.tet.2012.03.118 10.1021/jo00194a007 10.1021/ja057065s 10.1016/S1359-6446(03)02904-0 10.1016/0040-4039(96)00315-2 10.1039/c1cc11430a 10.1055/s-2006-942399 10.1021/jo00036a003 10.1007/3418_2011_28 10.1271/bbb.67.1559 10.1002/ps.2780410311 10.1146/annurev.ento.53.103106.093323 10.1002/anie.200704684 10.1002/anie.199712361 10.1021/op700239a 10.1002/adsc.200390002 10.1021/ja00271a037 10.1021/acs.cgd.1c00196 10.1055/s-2003-44365 10.1021/acs.chemrev.6b00798 10.1016/j.jfluchem.2007.07.016 10.1002/anie.197204601 10.1002/(SICI)1521-3773(19991203)38:23<3418::AID-ANIE3418>3.0.CO;2-V 10.1021/ja00068a095 10.1021/om2000508 10.1016/0040-4039(90)87006-L 10.1055/s-1995-4143 10.1002/anie.201002065 10.1021/ja00410a053 10.2533/chimia.1999.275 10.1002/1521-3773(20020617)41:12<1998::AID-ANIE1998>3.0.CO;2-8 10.1007/s10886-009-9737-y 10.1002/anie.201302349 10.1039/c2gc35160a 10.1021/ja0214882 10.1016/S1381-1169(00)00358-7 10.1016/S0360-0564(02)47005-8 10.1039/c1cs15093f 10.1126/science.1121977 10.1021/cr00039a008 10.1021/ja001923x 10.1016/S0957-4166(00)82375-7 10.1021/cr040700c 10.1039/D0QO00794C 10.1021/om00050a060 10.1271/bbb.60.1925 10.1002/anie.200400650 10.1039/C8CC02286K 10.1021/ja000163n 10.1039/C8CC09706B 10.1002/hlca.19900730215 10.1016/0040-4039(95)01924-7 10.1002/(SICI)1096-9063(199601)46:1<11::AID-PS336>3.0.CO;2-4 10.1002/cbdv.201100288 10.1002/ps.2780070306 10.1021/acs.accounts.6b00070 10.1016/j.tet.2011.05.015 10.1002/hlca.19240070124 10.1055/s-1995-5283 10.1021/cr00032a009 10.1016/j.chemosphere.2013.09.052 10.1021/ja00538a077 10.1021/ja00832a055 10.1021/jo00289a066 10.1021/bi000461x 10.1021/cr00013a009 10.1002/chem.200902238 10.1021/op970030v 10.1021/jf803828w 10.1021/es203320x 10.1021/jo9820871 10.1002/1521-3765(20011217)7:24<5246::AID-CHEM5246>3.0.CO;2-O 10.1055/s-0029-1216855 10.1021/cr0784083 10.1039/C6AY02015A 10.1016/j.enzmictec.2019.109493 10.1126/science.170.3953.87 10.1055/s-2005-869903 10.1002/(SICI)1521-3773(19990201)38:3<336::AID-ANIE336>3.0.CO;2-P 10.1021/acs.est.7b06540 10.2174/138527206778742687 10.1002/anie.200200556 10.1016/0957-4166(95)00414-9 10.1016/j.tet.2011.06.015 10.1038/nrd915 10.1016/0040-4020(82)85149-1 10.1002/ps.5052 10.1515/psr-2018-0097 10.1002/tcr.201402023 10.1021/cr3001803 10.1016/j.procbio.2018.03.011 |
| ContentType | Journal Article |
| Copyright | 2021 American Chemical Society |
| Copyright_xml | – notice: 2021 American Chemical Society |
| DBID | CGR CUY CVF ECM EIF NPM AAYXX CITATION 7X8 |
| DOI | 10.1021/acs.jafc.1c05553 |
| DatabaseName | Medline MEDLINE MEDLINE (Ovid) MEDLINE MEDLINE PubMed CrossRef MEDLINE - Academic |
| DatabaseTitle | MEDLINE Medline Complete MEDLINE with Full Text PubMed MEDLINE (Ovid) CrossRef MEDLINE - Academic |
| DatabaseTitleList | MEDLINE |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database – sequence: 2 dbid: EIF name: MEDLINE url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/medline/basic-search sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Agriculture |
| EISSN | 1520-5118 |
| EndPage | 14780 |
| ExternalDocumentID | 10_1021_acs_jafc_1c05553 34847666 b832052419 |
| Genre | Journal Article Review |
| GroupedDBID | - 4.4 55A 5GY 5VS 7~N 85S AABXI ABFLS ABFRP ABMVS ABUCX ACGFS ACJ ACS AEESW AENEX AFEFF AHGAQ ALMA_UNASSIGNED_HOLDINGS AQSVZ CS3 DU5 EBS ED F5P GGK GNL GX1 IH9 JG K2 LG6 P2P ROL TWZ UI2 VF5 VG9 W1F WH7 X --- -~X .K2 AAHBH ABJNI ABQRX ACGFO ADHLV AGXLV BAANH CGR CUPRZ CUY CVF ECM ED~ EIF JG~ NPM AAYXX CITATION 7X8 |
| ID | FETCH-LOGICAL-a336t-954f305c6bae02b7a80105d3bcbf15fa23a97c509d63744d237b4155393fae9a3 |
| IEDL.DBID | ACS |
| ISSN | 0021-8561 |
| IngestDate | Fri Aug 16 10:48:21 EDT 2024 Wed Sep 18 12:55:19 EDT 2024 Sat Sep 28 08:26:49 EDT 2024 Fri Dec 17 03:11:36 EST 2021 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 49 |
| Keywords | chiral agrochemicals pheromones insecticides catalytic asymmetric synthesis herbicides enantioselective |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-a336t-954f305c6bae02b7a80105d3bcbf15fa23a97c509d63744d237b4155393fae9a3 |
| Notes | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-3 content type line 23 ObjectType-Review-1 |
| ORCID | 0000-0002-7815-9607 |
| PMID | 34847666 |
| PQID | 2605227923 |
| PQPubID | 23479 |
| PageCount | 20 |
| ParticipantIDs | proquest_miscellaneous_2605227923 crossref_primary_10_1021_acs_jafc_1c05553 pubmed_primary_34847666 acs_journals_10_1021_acs_jafc_1c05553 |
| PublicationCentury | 2000 |
| PublicationDate | 20211215 2021-Dec-15 2021-12-15 |
| PublicationDateYYYYMMDD | 2021-12-15 |
| PublicationDate_xml | – month: 12 year: 2021 text: 20211215 day: 15 |
| PublicationDecade | 2020 |
| PublicationPlace | United States |
| PublicationPlace_xml | – name: United States |
| PublicationTitle | Journal of agricultural and food chemistry |
| PublicationTitleAlternate | J. Agric. Food Chem |
| PublicationYear | 2021 |
| Publisher | American Chemical Society |
| Publisher_xml | – name: American Chemical Society |
| References | ref99/cit99 ref3/cit3 ref81/cit81 ref16/cit16 ref185/cit185 ref23/cit23 ref115/cit115 ref187/cit187 ref181/cit181 ref111/cit111 ref113/cit113 ref183/cit183 ref117/cit117 ref48/cit48 ref74/cit74 ref189/cit189 ref119/cit119 ref10/cit10 ref35/cit35 ref93/cit93 ref42/cit42 ref120/cit120 ref178/cit178 ref122/cit122 ref61/cit61 ref176/cit176 ref67/cit67 ref128/cit128 ref124/cit124 ref126/cit126 ref54/cit54 ref137/cit137 ref11/cit11 ref102/cit102 ref29/cit29 ref174/cit174 ref86/cit86 ref170/cit170 ref5/cit5 ref43/cit43 ref133/cit133 ref28/cit28 ref148/cit148 ref144/cit144 ref167/cit167 ref163/cit163 ref66/cit66 ref22/cit22 ref87/cit87 ref106/cit106 ref190/cit190 ref140/cit140 ref194/cit194 ref98/cit98 ref153/cit153 ref150/cit150 ref63/cit63 ref56/cit56 ref155/cit155 ref156/cit156 ref158/cit158 ref8/cit8 ref59/cit59 ref85/cit85 ref34/cit34 ref37/cit37 ref60/cit60 ref17/cit17 ref82/cit82 ref147/cit147 ref145/cit145 ref21/cit21 ref166/cit166 ref164/cit164 Nguyen L. A. (ref4/cit4) 2006; 2 ref78/cit78 ref36/cit36 Ganai M. A. (ref135/cit135) 2017; 6 ref83/cit83 ref79/cit79 ref139/cit139 ref172/cit172 ref14/cit14 ref57/cit57 ref169/cit169 ref134/cit134 ref40/cit40 ref131/cit131 ref161/cit161 ref142/cit142 Wang Z. (ref143/cit143) 2012; 30 ref15/cit15 ref180/cit180 ref62/cit62 ref41/cit41 ref58/cit58 ref104/cit104 ref177/cit177 ref84/cit84 ref1/cit1 ref123/cit123 ref7/cit7 ref45/cit45 ref52/cit52 ref184/cit184 ref114/cit114 ref186/cit186 ref116/cit116 ref110/cit110 ref182/cit182 ref2/cit2 ref112/cit112 ref77/cit77 ref71/cit71 ref188/cit188 ref20/cit20 ref118/cit118 ref89/cit89 ref19/cit19 ref96/cit96 ref107/cit107 ref191/cit191 ref109/cit109 ref13/cit13 ref193/cit193 ref105/cit105 ref38/cit38 ref90/cit90 ref64/cit64 ref6/cit6 ref18/cit18 ref136/cit136 ref65/cit65 ref171/cit171 ref97/cit97 ref101/cit101 ref32/cit32 Oi R. (ref125/cit125) 1996; 73 ref39/cit39 ref168/cit168 ref132/cit132 ref91/cit91 ref12/cit12 Beller M. (ref55/cit55) 2004; 1 ref179/cit179 ref121/cit121 ref175/cit175 ref33/cit33 Spindler F. (ref76/cit76) 2006 ref129/cit129 ref44/cit44 ref70/cit70 ref9/cit9 ref152/cit152 ref154/cit154 ref27/cit27 ref151/cit151 ref159/cit159 ref92/cit92 ref157/cit157 ref31/cit31 ref88/cit88 ref160/cit160 ref53/cit53 ref149/cit149 ref162/cit162 ref46/cit46 ref49/cit49 ref75/cit75 ref24/cit24 ref141/cit141 ref50/cit50 ref138/cit138 ref100/cit100 ref25/cit25 ref173/cit173 ref103/cit103 ref72/cit72 ref51/cit51 ref68/cit68 ref94/cit94 ref130/cit130 ref146/cit146 ref26/cit26 ref73/cit73 ref69/cit69 ref165/cit165 ref95/cit95 ref108/cit108 ref192/cit192 ref30/cit30 ref47/cit47 ref127/cit127 Blaser H. U. (ref80/cit80) 1999; 53 |
| References_xml | – start-page: 1193 volume-title: The Handbook of Homogeneous Hydrogenation year: 2006 ident: ref76/cit76 doi: 10.1002/9783527619382.ch34 contributor: fullname: Spindler F. – ident: ref119/cit119 doi: 10.1016/j.envpol.2020.116269 – ident: ref88/cit88 – ident: ref117/cit117 doi: 10.7164/antibiotics.55.660 – ident: ref166/cit166 doi: 10.1021/ol200983s – ident: ref138/cit138 doi: 10.1016/S0957-4166(99)00082-8 – ident: ref14/cit14 doi: 10.1016/j.envpol.2010.03.014 – ident: ref53/cit53 doi: 10.1016/S1381-1169(98)00398-7 – ident: ref29/cit29 doi: 10.1021/cr0684016 – ident: ref95/cit95 doi: 10.1021/acs.orglett.6b00748 – ident: ref83/cit83 doi: 10.1016/j.tetasy.2005.01.033 – ident: ref84/cit84 doi: 10.1021/op050166q – ident: ref15/cit15 doi: 10.1016/j.jpba.2017.08.011 – ident: ref61/cit61 doi: 10.1021/acscatal.5b02846 – ident: ref81/cit81 doi: 10.1002/anie.199111933 – ident: ref104/cit104 – ident: ref10/cit10 doi: 10.1016/j.scitotenv.2020.141600 – volume: 6 start-page: 2552 year: 2017 ident: ref135/cit135 publication-title: Journal of Pharmacognosy and Phytochemistry contributor: fullname: Ganai M. A. – ident: ref8/cit8 doi: 10.1002/(SICI)1096-9063(199601)46:1<3::AID-PS337>3.0.CO;2-J – ident: ref193/cit193 doi: 10.1134/S1070428016050250 – ident: ref37/cit37 doi: 10.1021/acs.jafc.0c04163 – ident: ref70/cit70 doi: 10.1007/BF00394580 – ident: ref150/cit150 doi: 10.1073/pnas.86.4.1421 – ident: ref146/cit146 doi: 10.1016/S0040-4039(00)79002-2 – ident: ref103/cit103 doi: 10.1021/jacs.6b10690 – ident: ref153/cit153 doi: 10.1021/cr0100188 – ident: ref174/cit174 doi: 10.1039/c0gc00788a – ident: ref102/cit102 doi: 10.1021/cr400037u – ident: ref194/cit194 doi: 10.1016/S0957-4166(99)00482-6 – ident: ref49/cit49 doi: 10.1080/00397910903395243 – ident: ref34/cit34 doi: 10.1126/science.259.5094.479 – ident: ref130/cit130 doi: 10.1021/np000597w – ident: ref136/cit136 doi: 10.1016/S0040-4020(01)87778-4 – ident: ref177/cit177 doi: 10.1039/c3cc44122a – ident: ref93/cit93 doi: 10.1021/acs.accounts.7b00007 – ident: ref56/cit56 doi: 10.1002/(SICI)1521-3773(20000417)39:8<1428::AID-ANIE1428>3.0.CO;2-K – ident: ref1/cit1 doi: 10.1002/anie.200300599 – ident: ref179/cit179 doi: 10.1021/ol006976y – ident: ref147/cit147 doi: 10.1016/S0040-4039(00)73251-5 – ident: ref82/cit82 doi: 10.1016/S0040-4020(01)86523-6 – ident: ref44/cit44 doi: 10.6023/cjoc201903044 – ident: ref11/cit11 doi: 10.3390/molecules24061023 – ident: ref99/cit99 – ident: ref33/cit33 doi: 10.1351/pac200173010103 – ident: ref75/cit75 doi: 10.1007/s41061-016-0032-4 – ident: ref110/cit110 doi: 10.1016/j.tetasy.2015.03.006 – ident: ref7/cit7 doi: 10.1351/pac199769061335 – ident: ref67/cit67 doi: 10.1021/jacs.7b07188 – ident: ref17/cit17 doi: 10.1016/j.crci.2007.01.003 – volume: 30 start-page: 23 year: 2012 ident: ref143/cit143 publication-title: Chin. J. Chem. doi: 10.1002/cjoc.201100482 contributor: fullname: Wang Z. – ident: ref62/cit62 doi: 10.1021/ja00253a051 – ident: ref131/cit131 doi: 10.1016/S0957-4166(03)00519-6 – ident: ref50/cit50 doi: 10.1016/j.molcata.2004.09.053 – ident: ref118/cit118 doi: 10.1016/j.tetasy.2009.10.030 – ident: ref190/cit190 doi: 10.1002/1099-0690(200103)2001:6<1143::AID-EJOC1143>3.0.CO;2-O – ident: ref105/cit105 doi: 10.1021/acs.oprd.9b00466 – volume: 2 start-page: 85 year: 2006 ident: ref4/cit4 publication-title: Int. J. Biomed Sci. doi: 10.59566/IJBS.2006.2085 contributor: fullname: Nguyen L. A. – ident: ref91/cit91 doi: 10.1002/anie.202006648 – ident: ref109/cit109 doi: 10.3390/molecules15021041 – ident: ref32/cit32 doi: 10.1016/S0926-860X(01)00801-8 – ident: ref79/cit79 doi: 10.1515/znb-1982-0411 – ident: ref156/cit156 doi: 10.1080/00304940903507788 – ident: ref43/cit43 doi: 10.1039/C6QO00641H – ident: ref86/cit86 doi: 10.1002/adsc.200390000 – ident: ref126/cit126 doi: 10.1021/ja00185a050 – ident: ref12/cit12 doi: 10.1021/tx500481n – ident: ref90/cit90 doi: 10.1017/S0890037X00033935 – ident: ref87/cit87 doi: 10.1002/(SICI)1096-9063(1998110)54:3<302::AID-PS831>3.0.CO;2-3 – ident: ref160/cit160 doi: 10.1016/j.tet.2008.04.079 – ident: ref74/cit74 doi: 10.1021/cr100218m – ident: ref111/cit111 doi: 10.1016/0040-4039(95)01769-E – ident: ref115/cit115 doi: 10.1021/np0200865 – ident: ref96/cit96 doi: 10.1002/anie.200500784 – ident: ref149/cit149 doi: 10.1016/S0957-4166(00)80506-6 – ident: ref77/cit77 doi: 10.1023/A:1019164928084 – volume: 73 start-page: 1 year: 1996 ident: ref125/cit125 publication-title: Org. Synth. doi: 10.15227/orgsyn.073.0001 contributor: fullname: Oi R. – ident: ref128/cit128 doi: 10.1016/j.tetasy.2017.07.004 – ident: ref52/cit52 doi: 10.1016/0957-4166(95)00178-R – ident: ref123/cit123 doi: 10.1016/S0040-4039(00)78093-2 – ident: ref181/cit181 doi: 10.1016/S0040-4039(00)60957-7 – ident: ref188/cit188 doi: 10.1039/C39950002391 – ident: ref192/cit192 doi: 10.1023/A:1005447922939 – ident: ref31/cit31 doi: 10.1155/2014/402860 – ident: ref157/cit157 doi: 10.1002/chem.201604564 – ident: ref116/cit116 doi: 10.1016/0040-4039(96)01589-4 – ident: ref64/cit64 doi: 10.1021/ar7000809 – ident: ref108/cit108 doi: 10.1055/s-1986-31489 – ident: ref155/cit155 doi: 10.1021/cr200073d – ident: ref176/cit176 doi: 10.1055/s-2001-18074 – ident: ref137/cit137 doi: 10.1039/a907396e – ident: ref24/cit24 doi: 10.3390/catal9100802 – ident: ref73/cit73 doi: 10.1021/jo00005a024 – ident: ref151/cit151 doi: 10.1016/S0040-4039(00)61433-8 – ident: ref60/cit60 doi: 10.1021/ja106674n – ident: ref161/cit161 doi: 10.1055/s-0033-1340838 – ident: ref66/cit66 doi: 10.1016/j.tet.2012.03.118 – ident: ref107/cit107 doi: 10.1021/jo00194a007 – ident: ref59/cit59 doi: 10.1021/ja057065s – ident: ref5/cit5 doi: 10.1016/S1359-6446(03)02904-0 – ident: ref165/cit165 doi: 10.1016/0040-4039(96)00315-2 – ident: ref101/cit101 doi: 10.1039/c1cc11430a – ident: ref25/cit25 doi: 10.1055/s-2006-942399 – ident: ref129/cit129 doi: 10.1021/jo00036a003 – ident: ref35/cit35 doi: 10.1016/j.scitotenv.2020.141600 – ident: ref39/cit39 doi: 10.1007/3418_2011_28 – ident: ref139/cit139 doi: 10.1271/bbb.67.1559 – ident: ref72/cit72 doi: 10.1002/ps.2780410311 – ident: ref133/cit133 doi: 10.1146/annurev.ento.53.103106.093323 – ident: ref169/cit169 doi: 10.1002/anie.200704684 – ident: ref173/cit173 doi: 10.1002/anie.199712361 – ident: ref19/cit19 doi: 10.1021/op700239a – ident: ref30/cit30 doi: 10.1002/adsc.200390002 – ident: ref182/cit182 doi: 10.1021/ja00271a037 – ident: ref78/cit78 doi: 10.1021/acs.cgd.1c00196 – ident: ref26/cit26 doi: 10.1055/s-2003-44365 – ident: ref158/cit158 doi: 10.1021/acs.chemrev.6b00798 – ident: ref167/cit167 doi: 10.1016/j.jfluchem.2007.07.016 – ident: ref89/cit89 doi: 10.1002/anie.197204601 – ident: ref18/cit18 doi: 10.1002/(SICI)1521-3773(19991203)38:23<3418::AID-ANIE3418>3.0.CO;2-V – ident: ref48/cit48 doi: 10.1021/ja00068a095 – ident: ref40/cit40 doi: 10.1021/om2000508 – ident: ref189/cit189 doi: 10.1016/0040-4039(90)87006-L – ident: ref114/cit114 doi: 10.1055/s-1995-4143 – ident: ref187/cit187 doi: 10.1002/anie.201002065 – ident: ref100/cit100 – ident: ref122/cit122 doi: 10.1021/ja00410a053 – volume: 53 start-page: 275 year: 1999 ident: ref80/cit80 publication-title: Chimia doi: 10.2533/chimia.1999.275 contributor: fullname: Blaser H. U. – ident: ref63/cit63 doi: 10.1002/1521-3773(20020617)41:12<1998::AID-ANIE1998>3.0.CO;2-8 – ident: ref132/cit132 doi: 10.1007/s10886-009-9737-y – ident: ref97/cit97 doi: 10.1002/anie.201302349 – ident: ref170/cit170 doi: 10.1039/c2gc35160a – ident: ref184/cit184 doi: 10.1021/ja0214882 – ident: ref57/cit57 doi: 10.1016/S1381-1169(00)00358-7 – ident: ref42/cit42 doi: 10.1016/S0360-0564(02)47005-8 – ident: ref98/cit98 – ident: ref92/cit92 doi: 10.1039/c1cs15093f – ident: ref65/cit65 doi: 10.1126/science.1121977 – ident: ref51/cit51 doi: 10.1021/cr00039a008 – ident: ref175/cit175 doi: 10.1021/ja001923x – ident: ref47/cit47 doi: 10.1016/S0957-4166(00)82375-7 – ident: ref6/cit6 doi: 10.1021/cr040700c – ident: ref69/cit69 doi: 10.1039/D0QO00794C – ident: ref46/cit46 doi: 10.1021/om00050a060 – ident: ref13/cit13 doi: 10.1271/bbb.60.1925 – ident: ref27/cit27 doi: 10.1016/0040-4039(90)87006-L – ident: ref168/cit168 doi: 10.1002/anie.200400650 – ident: ref162/cit162 doi: 10.1039/C8CC02286K – ident: ref94/cit94 doi: 10.1021/ja000163n – ident: ref191/cit191 doi: 10.1039/C8CC09706B – ident: ref180/cit180 doi: 10.1002/hlca.19900730215 – ident: ref68/cit68 doi: 10.1021/jacs.6b10690 – ident: ref163/cit163 doi: 10.1016/0040-4039(95)01924-7 – ident: ref2/cit2 doi: 10.1002/(SICI)1096-9063(199601)46:1<11::AID-PS336>3.0.CO;2-4 – ident: ref112/cit112 doi: 10.1002/cbdv.201100288 – ident: ref54/cit54 doi: 10.1002/ps.2780070306 – ident: ref159/cit159 doi: 10.1021/acs.accounts.6b00070 – ident: ref140/cit140 doi: 10.1016/j.tet.2011.05.015 – ident: ref152/cit152 doi: 10.1002/hlca.19240070124 – ident: ref164/cit164 doi: 10.1055/s-1995-5283 – ident: ref148/cit148 doi: 10.1021/cr00032a009 – ident: ref120/cit120 doi: 10.1016/j.chemosphere.2013.09.052 – ident: ref106/cit106 doi: 10.1021/ja00538a077 – ident: ref142/cit142 doi: 10.1021/ja00832a055 – ident: ref124/cit124 doi: 10.1021/jo00289a066 – ident: ref144/cit144 doi: 10.1021/bi000461x – ident: ref22/cit22 doi: 10.1021/cr00013a009 – ident: ref41/cit41 doi: 10.1002/chem.200902238 – ident: ref127/cit127 doi: 10.1021/op970030v – ident: ref134/cit134 doi: 10.1021/jf803828w – ident: ref9/cit9 doi: 10.1021/es203320x – ident: ref28/cit28 doi: 10.1021/jo9820871 – volume: 1 start-page: 28 volume-title: Transition Metal-Catalyzed Reactions year: 2004 ident: ref55/cit55 contributor: fullname: Beller M. – ident: ref172/cit172 doi: 10.1002/1521-3765(20011217)7:24<5246::AID-CHEM5246>3.0.CO;2-O – ident: ref145/cit145 doi: 10.1055/s-0029-1216855 – ident: ref154/cit154 doi: 10.1021/cr0784083 – ident: ref23/cit23 doi: 10.1039/C6AY02015A – ident: ref71/cit71 doi: 10.1016/j.enzmictec.2019.109493 – ident: ref121/cit121 – ident: ref141/cit141 doi: 10.1126/science.170.3953.87 – ident: ref20/cit20 doi: 10.1055/s-2005-869903 – ident: ref38/cit38 doi: 10.1002/(SICI)1521-3773(19990201)38:3<336::AID-ANIE336>3.0.CO;2-P – ident: ref36/cit36 doi: 10.1021/acs.est.7b06540 – ident: ref21/cit21 doi: 10.2174/138527206778742687 – ident: ref185/cit185 doi: 10.1002/anie.200200556 – ident: ref58/cit58 doi: 10.1016/0957-4166(95)00414-9 – ident: ref113/cit113 doi: 10.1016/j.tet.2011.06.015 – ident: ref3/cit3 doi: 10.1038/nrd915 – ident: ref178/cit178 doi: 10.1016/0040-4020(82)85149-1 – ident: ref16/cit16 doi: 10.1002/ps.5052 – ident: ref171/cit171 doi: 10.1515/psr-2018-0097 – ident: ref186/cit186 doi: 10.1002/tcr.201402023 – ident: ref45/cit45 doi: 10.1021/cr3001803 – ident: ref183/cit183 doi: 10.1055/s-0029-1216855 – ident: ref85/cit85 doi: 10.1016/j.procbio.2018.03.011 |
| SSID | ssj0008570 |
| Score | 2.4899971 |
| SecondaryResourceType | review_article |
| Snippet | Catalytic asymmetric synthesis has become an essential tool for the enantioselective synthesis of pharmaceuticals, natural products, and agrochemicals (mainly... |
| SourceID | proquest crossref pubmed acs |
| SourceType | Aggregation Database Index Database Publisher |
| StartPage | 14761 |
| SubjectTerms | Agrochemicals Biological Products Catalysis Crop Protection Fungicides, Industrial |
| Title | Developments in the Catalytic Asymmetric Synthesis of Agrochemicals and Their Synthetic Importance |
| URI | http://dx.doi.org/10.1021/acs.jafc.1c05553 https://www.ncbi.nlm.nih.gov/pubmed/34847666 https://search.proquest.com/docview/2605227923 |
| Volume | 69 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwjV3JTsMwELVYLnBgX8omI8GBg0tjO9uxqqgACS6A1Fs0dmxUUFOE20P5esZJ2Bf1mtijZGbsefaM3hByBBp4rqRlYFohkynkDCKrmFYhJMCTRJe9CK6uo_M7edkLex80Od8z-Dw4Be2aD2B1M9CenErMknnuCwg9DOrcvO-6nqi9KucIWIKgoE5J_ibBByLtvgaiP9BlGWW6y1W7IleSE_riksfmeKSa-uUndeMUP7BClmqwSduVd6ySGVOskcX2_XNNuGHWifpUNeRov6AICGnH3-lMcBJtu8lg4JtuaXozKfCd6zs6tBRl-FZbJdeAo1Dk9NZnHOpBfubFoET26FMb5K57dts5Z3XfBQZCRCOWhtLiNqAjhQbkKobEt9HMhdLKBqEFLiCNNSKNPBKxlDkXsfK4RKTCgklBbJK5YliYbUKltMrgIUQAIFQJWwryGCFSpMKWESq2DXKM6snqdeOyMiXOg6x8iDrLap01yMmbsbKniobjn7GHb9bMcK34BAgUZjh2mT-7VYyJDbJVmfldmpAYp_EstzPlF-2SBe59LeAsCPfI3Oh5bPYRn4zUQemYrwcn4NA |
| link.rule.ids | 315,786,790,2782,27109,27957,27958,57093,57143 |
| linkProvider | American Chemical Society |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1LbxMxEB6V9gA9QMujBCgYCQ4cHLJrex_HKKJKoe2BplJvq7HXrgrKBtXJIfx6xt5NKIhW9Oq1R17P2PPNjvcbgHdoMK21dBztQHFZYs0xc5obrbDAtChMrEVwfJKNz-Tnc3W-AcnqXxiahCdJPibxf7MLJB9D2zd0pp-YwFEl7sGWyikcD2hodLo-fANfe3urI-EFYYMuM_kvCcEfGf-nP7oBZEZnc_AIvq6nGe-YfO8v5rpvfv7F4Hin99iBhx30ZMPWVnZhwzaPYXt4cdXRb9gnoK_dIfLssmEED9kofOFZ0iA29MvpNJTgMux02dAzf-nZzDGSEQpvReYBz7Cp2STkH7pOYeThNOJ8srCncHbwaTIa864KA0chsjkvlXR0KJhMkzpTnWMRimrWQhvtEuUwFVjmhnBHnYlcyjoVuQ4oRZTCoS1RPIPNZtbY58CkdNpSSCIQCbiogcY6J8CUaTWwQueuB-9peapuF_kqJsjTpIqNtGZVt2Y9-LDSWfWjJeW4pe_blVIr2jkhHYKNnS18FSK5lj-xB3utttfShCSvTZHdi_-c0Ru4P54cH1VHhydfXsKDNJhfkvJEvYLN-dXC7hNymevX0VZ_Aafy6Ts |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1LbxMxEB6VVkJwAMozbQEjwYGD0-za3scxShu1FCqktqi31dhro4KyqerkkP76jr2bCBBF5eq1R96ZsefzjvcbgPdoMK21dBztQHFZYs0xc5obrbDAtChMrEXw5Tg7OJOfztX5GqjlvzA0CU-SfEzih1V9WbuOYSDZDe0_0Jl-YgJPlbgHGyrU7w6IaHSy2oADZ3t7syPhBeGDLjv5NwkhJhn_e0y6BWjGgDN-DN9WU433TH725zPdN9d_sDj-97s8gUcdBGXD1mc2Yc02T-Hh8PtVR8Nhn4H-5S6RZxcNI5jIRuFLz4IGsaFfTCahFJdhJ4uGnvkLz6aOkYxQgCsyEHiGTc1OQx6i6xRGHk4i3idPew5n4_3T0QHvqjFwFCKb8VJJR5uDyTSZNdU5FqG4Zi200S5RDlOBZW4If9SZyKWsU5HrgFZEKRzaEsULWG-mjX0FTEqnLR1NBCIBGDXQWOcEnDKtBlbo3PXgA6mn6laTr2KiPE2q2Eg6qzqd9eDj0m7VZUvO8Y--75aGrWgFhbQINnY691U40bU8ij142Vp8JU1Iit50wtu644zewv2ve-Pq8-Hx0TY8SIMHJilP1A6sz67m9jUBmJl-E931Bi_u67U |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Developments+in+the+Catalytic+Asymmetric+Synthesis+of+Agrochemicals+and+Their+Synthetic+Importance&rft.jtitle=Journal+of+agricultural+and+food+chemistry&rft.au=Sharma%2C+Sandeep+Kumar&rft.au=Paniraj%2C+Alilugatta+Sheshagiri+Rao&rft.au=Tambe%2C+Yashwant+Bhikaji&rft.date=2021-12-15&rft.eissn=1520-5118&rft.volume=69&rft.issue=49&rft.spage=14761&rft.epage=14780&rft_id=info:doi/10.1021%2Facs.jafc.1c05553&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0021-8561&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0021-8561&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0021-8561&client=summon |